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The reaction was intended to proceed via a Fischer esterification of the chiral, optically pure alcohol A with the
draw a rxn mechanism to show why ester was formed instead and the optical activity was lost? What could the scientists have done to prevent ester formation?
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- Draw the structure of (Z)-1-bromo-1-chloro-1-butene. • Consider E/Z stereochemistry of alkenes. • You do not have to explicitly draw H atoms. AAVII ? ChemDoodle [F Ⓡ1) Which diene can undergo Diels-Alder reaction? gj d)70 ins210 V16225050 panx qalborgo 3) In a recently-published synthesis of yohimbine (used in folk medicine as an aphrodisiac), the Diels-Alder reaction was used to form a new ring during a key step. R OtBu Diels-Alder a. Draw a circle around the four atoms of the diene group in this molecule. b. Draw a square around the two atoms of the best dienophile group in this molecule. c. Draw the product of this reaction, ignoring stereochemistry.
- Need some help filling in the missing starting materials and products. Possibly dinophile, diene, or diels alder products.Diels–Alder reaction of a monosubstituted diene (such as CH2=CH–CH=CHOCH3) with a monosubstituted dienophile (such as CH2=CHCHO)gives a mixture of products, but the 1,2-disubstituted product oftenpredominates. Draw the resonance hybrid for each reactant, and use thecharge distribution of the hybrids to explain why the 1,2-disubstitutedproduct is the major product.2) Predict the major product for each Diels-Alder reaction. Include stereochemistry where appropriate. H. C=N (a) H H. CH3 CH;O, (b) Ph (c) Ph
- Which of the following will not act as diene reactant in a Diels Alder reaction? A) B) D) OCH3 H,CO AFor our Diels-Alder Reaction lab, they asked to provide heat to the structures and I'm a little unsure of what the products will look like, if you can help, please?Tips on how to approach a Diels Alder problem like this.