Note these acronyms: HOAC = Acetic Acid; NaOAc = Sodium Acetate; THF = tetrahydrofuran Ph = Phenyl = C6H5; DMSO = Dimethyl Sulfoxide, H3C-O-H = methanol, Zn = Zinc, D = heavy Hydrogen (1 proton and 1 neutron). Acetone = Acetic Acid = THF= Ph= CH3 HO, 1. Write the products of the following reactions. If there is no reaction write NR. For full credit clearly indicate cis or trans relationships in cyclic compounds, where appropriate. ( +к Мпо , кон, cold CHa + KMNO4, KOH, cold
Note these acronyms: HOAC = Acetic Acid; NaOAc = Sodium Acetate; THF = tetrahydrofuran Ph = Phenyl = C6H5; DMSO = Dimethyl Sulfoxide, H3C-O-H = methanol, Zn = Zinc, D = heavy Hydrogen (1 proton and 1 neutron). Acetone = Acetic Acid = THF= Ph= CH3 HO, 1. Write the products of the following reactions. If there is no reaction write NR. For full credit clearly indicate cis or trans relationships in cyclic compounds, where appropriate. ( +к Мпо , кон, cold CHa + KMNO4, KOH, cold
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Acronyms and Compounds:**
- **HOAc**: Acetic Acid
- **NaOAc**: Sodium Acetate
- **THF**: Tetrahydrofuran
- **Ph**: Phenyl = C₆H₅
- **DMSO**: Dimethyl Sulfoxide
- **H₃C-O-H**: Methanol
- **Zn**: Zinc
- **D**: Heavy Hydrogen (1 proton and 1 neutron)
**Structures:**
- **Acetone**:
- Structure: O=C(CH₃)₂
- **Acetic Acid**:
- Structure: O=C(CH₃)OH
- **THF**:
- Structure: Five-membered ring with one oxygen
- **Phenyl (Ph)**:
- Structure: Benzene ring (six-membered with alternating double bonds)
**Chemical Reactions:**
1. **Write the products of the following reactions. If there is no reaction, write NR. Clearly indicate cis or trans relationships in cyclic compounds, where appropriate.**
#### Reactions:
1. **Reaction 1:**
- **Starting Material**:
- Hexene structure with a terminal alkene group.
- **Reagent**:
- KMnO₄, KOH, cold
- **Expected Product**:
- Syn-diol product likely due to cold KMnO₄ addition.
2. **Reaction 2:**
- **Starting Material**:
- Cyclohexene with a methyl group.
- **Reagent**:
- KMnO₄, KOH, cold
- **Expected Product**:
- Syn-diol product on the cyclohexane ring.
3. **Reaction 3:**
- **Starting Material**:
- Heptene structure with an internal alkene.
- **Reagent**:
- H₂, 1 atm, RT, Ni (catalyst)
- **Expected Product**:
- Saturated alkane product through hydrogenation.
4. **Reaction 4:**
- **Starting Material**:
- Cyclohexene with phenyl group attached.
- **Reagent**:
- H₂, 1 atm, RT
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