но OH HO но maleic acid fumaric açid mp (°C) solubility (g/L) in H20 at 25 °C pKa1 130 286 788 7 1.9 3.0 pKa2 6.5 4.5

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There is restricted rotation around carboncarbon double bonds. Maleic acid and fumaric acid are two isomers with vastly different physical properties and pKa values for loss of both protons. Explain why each of these differences occurs.

(See attachment)

но
OH
HO
но
maleic acid
fumaric açid
mp (°C)
solubility (g/L) in H20 at 25 °C
pKa1
130
286
788
7
1.9
3.0
pKa2
6.5
4.5
Transcribed Image Text:но OH HO но maleic acid fumaric açid mp (°C) solubility (g/L) in H20 at 25 °C pKa1 130 286 788 7 1.9 3.0 pKa2 6.5 4.5
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