NH3 (9) +HC1(g) NH, CI(s) %3D (PNH, ) (PHCI) OK=PNH, (PNH,) (PHCI) K %3D (PNH, ) (PHCI) OK = (PNH,)(Pac1) K: (PNH )

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Write equilibrium constant (K) expressions for the following reactions:  C and D

C: 4NO2 (g) + 6H2O (g) ---> <---- 4NH3 (g) + 7O2 (g)

D: attached Below 

### Equilibrium Constant Expression

Given the chemical reaction:
\[ \text{NH}_3(g) + \text{HCl}(g) \leftrightarrow \text{NH}_4\text{Cl}(s) \]

Determine the correct expression for the equilibrium constant \( K \).

**Options:**

1. \( K = \frac{P_{\text{NH}_4\text{Cl}}}{(P_{\text{NH}_3})(P_{\text{HCl}})} \)
2. \( K = P_{\text{NH}_3} \)
3. \( K = \frac{(P_{\text{NH}_3})(P_{\text{HCl}})}{P_{\text{NH}_4\text{Cl}}} \)
4. \( K = \frac{1}{(P_{\text{NH}_3})(P_{\text{HCl}})} \)
5. \( K = (P_{\text{NH}_3})(P_{\text{HCl}}) \)
6. \( K = \frac{1}{P_{\text{NH}_3}} \)

### Explanation of Symbols

- \( P_{\text{NH}_3} \): Partial pressure of ammonia gas \( \text{NH}_3 \).
- \( P_{\text{HCl}} \): Partial pressure of hydrogen chloride gas \( \text{HCl} \).
- \( P_{\text{NH}_4\text{Cl}} \): Partial pressure of ammonium chloride \( \text{NH}_4\text{Cl} \) (however, since \( \text{NH}_4\text{Cl} \) is a solid, its activity is considered constant and does not appear in the equilibrium expression).

### Understanding the Equilibrium Constant, \( K \)

The equilibrium constant, \( K \), for the reaction involving gases is generally given by the ratio of the partial pressures (or concentrations, in case of solutions) of the products to the reactants, each raised to the power of their respective coefficients in the balanced chemical equation.

Since \( \text{NH}_4\text{Cl} \) is a solid, it does not appear in the expression for the equilibrium constant for this reaction. Therefore, the correct expression for the equilibrium constant \( K \) is:
\[ K = \frac{1}{(P_{\text{NH}_3})(P_{\text{H
Transcribed Image Text:### Equilibrium Constant Expression Given the chemical reaction: \[ \text{NH}_3(g) + \text{HCl}(g) \leftrightarrow \text{NH}_4\text{Cl}(s) \] Determine the correct expression for the equilibrium constant \( K \). **Options:** 1. \( K = \frac{P_{\text{NH}_4\text{Cl}}}{(P_{\text{NH}_3})(P_{\text{HCl}})} \) 2. \( K = P_{\text{NH}_3} \) 3. \( K = \frac{(P_{\text{NH}_3})(P_{\text{HCl}})}{P_{\text{NH}_4\text{Cl}}} \) 4. \( K = \frac{1}{(P_{\text{NH}_3})(P_{\text{HCl}})} \) 5. \( K = (P_{\text{NH}_3})(P_{\text{HCl}}) \) 6. \( K = \frac{1}{P_{\text{NH}_3}} \) ### Explanation of Symbols - \( P_{\text{NH}_3} \): Partial pressure of ammonia gas \( \text{NH}_3 \). - \( P_{\text{HCl}} \): Partial pressure of hydrogen chloride gas \( \text{HCl} \). - \( P_{\text{NH}_4\text{Cl}} \): Partial pressure of ammonium chloride \( \text{NH}_4\text{Cl} \) (however, since \( \text{NH}_4\text{Cl} \) is a solid, its activity is considered constant and does not appear in the equilibrium expression). ### Understanding the Equilibrium Constant, \( K \) The equilibrium constant, \( K \), for the reaction involving gases is generally given by the ratio of the partial pressures (or concentrations, in case of solutions) of the products to the reactants, each raised to the power of their respective coefficients in the balanced chemical equation. Since \( \text{NH}_4\text{Cl} \) is a solid, it does not appear in the expression for the equilibrium constant for this reaction. Therefore, the correct expression for the equilibrium constant \( K \) is: \[ K = \frac{1}{(P_{\text{NH}_3})(P_{\text{H
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