Need help providing an assignment for the IR spectra provided for the Diels-Alder adduct 3 (mechanism included to show what 3 is) using the following table. Thank you :) entry wavenumber strength functional group 1       2       3       4       5

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Need help providing an assignment for the IR spectra provided for the Diels-Alder adduct 3 (mechanism included to show what 3 is) using the following table. Thank you :)

entry

wavenumber

strength

functional group

1

 

 

 

2

 

 

 

3

 

 

 

4

 

 

 

5

 

 

 

 

Preparation of the Diels-Alder product (3)
ethyl acetate, rt, 168 h
+
N-Ph
Ph
1
2
3
Transcribed Image Text:Preparation of the Diels-Alder product (3) ethyl acetate, rt, 168 h + N-Ph Ph 1 2 3
Diels - Alder
-5
-10
-15
-20
-25
-30
-35
-40
-45
-50
-55-
-60
-65-
3800
3600
3400
3200
3000
2800
2600
2400
2200
2000
1800
1600
1400
1200
1000
800
Wavenumber
Name
Diels -Alder
%Transmittance
0967
8987
1770
1302
1189
811-
Transcribed Image Text:Diels - Alder -5 -10 -15 -20 -25 -30 -35 -40 -45 -50 -55- -60 -65- 3800 3600 3400 3200 3000 2800 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Wavenumber Name Diels -Alder %Transmittance 0967 8987 1770 1302 1189 811-
Expert Solution
Description

 

For the above 3 structures, the IR stretching frequency data is as follows:

CH stretching in alkene = 3000-3100 cm-1 CC stretching in cyclic alkene =1566-1600 cm-1Cyclic amides = 1700 cm-1CC bending = 630-700 cm-1CH bending =650-750 cm-1

The stretching frequency has been reduced for the amide due to intense conjugation with co and phenyl ring. 

And similarly for the alkene due to conjugation the stretching frequency is lesser than normal.

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