Shown below is an example of another Diels-Alder reaction performed by James H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which results in two products. Although in this article the reaction shows relatively low selectivity between the between the thermodynamic and kinetic products, a recent publication by other authors show that this reaction can be performed in 10 minutes with the help of microwaves (yes, microwaves!) with great selectivity. Point out the kinetic and thermodynamic products. Explain your choices with the help of an energy profile diagram. Draw the transition state structure for each product. (Hint: The recent article cites Cooley and Williams work as a reference) 3. N-Ph N-Ph
Shown below is an example of another Diels-Alder reaction performed by James H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which results in two products. Although in this article the reaction shows relatively low selectivity between the between the thermodynamic and kinetic products, a recent publication by other authors show that this reaction can be performed in 10 minutes with the help of microwaves (yes, microwaves!) with great selectivity. Point out the kinetic and thermodynamic products. Explain your choices with the help of an energy profile diagram. Draw the transition state structure for each product. (Hint: The recent article cites Cooley and Williams work as a reference) 3. N-Ph N-Ph
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.24E: Which of the following molecules should have pure rotational spectra? a Dimethyltriacetylene,...
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Transcribed Image Text:Shown below is an example of another Diels-Alder reaction performed by James
H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which
results in two products. Although in this article the reaction shows relatively low
selectivity between the between the thermodynamic and kinetic products, a recent
publication by other authors show that this reaction can be performed in 10 minutes
with the help of microwaves (yes, microwaves!) with great selectivity. Point out the
kinetic and thermodynamic products. Explain your choices with the help of an energy
profile diagram. Draw the transition state structure for each product. (Hint: The recent
article cites Cooley and Williams work as a reference)
3.
N-Ph
-Ph
Ph
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