Shown below is an example of another Diels-Alder reaction performed by James H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which results in two products. Although in this article the reaction shows relatively low selectivity between the between the thermodynamic and kinetic products, a recent publication by other authors show that this reaction can be performed in 10 minutes with the help of microwaves (yes, microwaves!) with great selectivity. Point out the kinetic and thermodynamic products. Explain your choices with the help of an energy profile diagram. Draw the transition state structure for each product. (Hint: The recent article cites Cooley and Williams work as a reference) 3. N-Ph N-Ph
Shown below is an example of another Diels-Alder reaction performed by James H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which results in two products. Although in this article the reaction shows relatively low selectivity between the between the thermodynamic and kinetic products, a recent publication by other authors show that this reaction can be performed in 10 minutes with the help of microwaves (yes, microwaves!) with great selectivity. Point out the kinetic and thermodynamic products. Explain your choices with the help of an energy profile diagram. Draw the transition state structure for each product. (Hint: The recent article cites Cooley and Williams work as a reference) 3. N-Ph N-Ph
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section20.3: Uv-visible Spectroscopy
Problem 20.5P
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Transcribed Image Text:Shown below is an example of another Diels-Alder reaction performed by James
H. Cooley and Richard Vaughan Williams (J. Chem. Educ. 1997, 74, 5, 582) which
results in two products. Although in this article the reaction shows relatively low
selectivity between the between the thermodynamic and kinetic products, a recent
publication by other authors show that this reaction can be performed in 10 minutes
with the help of microwaves (yes, microwaves!) with great selectivity. Point out the
kinetic and thermodynamic products. Explain your choices with the help of an energy
profile diagram. Draw the transition state structure for each product. (Hint: The recent
article cites Cooley and Williams work as a reference)
3.
N-Ph
-Ph
Ph
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