Organic Chemistry 9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: John E. McMurry
1 Structure And Bonding 2 Polar Covalent Bonds; Acids And Bases 3 Organic Compounds: Alkanes And Their Stereochemistry 4 Organic Compounds: Cycloalkanes And Their Stereochemistry 5 Stereochemistry At Tetrahedral Centers 6 An Overview Of Organic Reactions 7 Alkenes: Structure And Reactivity 8 Alkenes: Reactions And Synthesis 9 Alkynes: An Introduction To Organic Synthesis 10 Organohalides 11 Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations 12 Structure Determination: Mass Spectrometry And Infrared Spectroscopy 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy 14 Conjugated Compounds And Ultraviolet Spectroscopy 15 Benzene And Aromaticity 16 Chemistry Of Benzene: Electrophilic Aromatic Substitution 17 Alcohols And Phenols 18 Ethers And Epoxides; Thiols And Sulfides 19 Aldehydes And Ketones: Nucleophilic Addition Reactions 20 Carboxylic Acids And Nitriles 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions 22 Carbonyl Alpha-substitution Reactions 23 Carbonyl Condensation Reactions 24 Amines And Heterocycles 25 Biomolecules: Carbohydrates 26 Biomolecules: Amino Acids, Peptides, And Proteins 27 Biomolecules: Lipids 28 Biomolecules: Nucleic Acids 29 The Organic Chemistry Of Metabolic Pathways 30 Orbitals And Organic Chemistry: Pericyclic Reactions 31 Synthetic Polymers Chapter23: Carbonyl Condensation Reactions
23.1 Carbonyl Condensations: The Aldol Reaction 23.2 Carbonyl Condensations Versus Alpha Substitutions 23.3 Dehydration Of Aldol Products: Synthesis Of Enones 23.4 Using Aldol Reactions In Synthesis 23.5 Mixed Aldol Reactions 23.6 Intramolecular Aldol Reactions 23.7 The Claisen Condensation Reaction 23.8 Mixed Claisen Condensations 23.9 Intramolecular Claisen Condensations: The Dieckmann Cyclization 23.10 Conjugate Carbonyl Additions: The Michael Reaction 23.11 Carbonyl Condensations With Enamines: The Stork Reaction 23.12 The Robinson Annulation Reaction 23.13 Some Biological Carbonyl Condensation Reactions 23.SE Something Extra Section23.SE: Something Extra
Problem 23VC Problem 24VC Problem 25VC Problem 26VC: The following molecule was formed by a Robinson annulation reaction. What reactants were used? Problem 27MP Problem 28MP Problem 29MP: Predict the product(s) and provide the mechanism for each reaction below: Problem 30MP: Predict the product(s) and provide the mechanism for each reaction below. Problem 31MP: Predict the product(s) and provide the mechanism for each reaction below. Problem 32MP: Knoevenagel condensation is a reaction involving an active methylene compound (a CH2 flanked by two... Problem 33MP: Azlactones are important starting materials used in the synthesis of dehydro α-aminoacids. They... Problem 34MP Problem 35MP: Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that... Problem 36MP: The first step in the citric acid cycle of food metabolism is reaction of oxaloacetate with acetyl... Problem 37MP Problem 38MP: The Knoevenagel reaction is a carbonyl condensation reaction of an ester with an aldehyde or ketone... Problem 39MP: The Darzens reaction invoIves a two-step, base-catalyzed condensation of ethyl chloroacetate with a... Problem 40MP: The following reaction involves a hydrolysis followed by an intramolecular nucleophilic acyl... Problem 41MP Problem 42MP Problem 43MP Problem 44MP: Propose a mechanism for the following base-catalyzed isomerization: Problem 45MP Problem 46MP Problem 47MP Problem 48AP Problem 49AP Problem 50AP Problem 51AP Problem 52AP Problem 53AP Problem 54AP Problem 55AP Problem 56AP Problem 57AP Problem 58AP Problem 59AP: In the mixed Claisen reaction of cyclopentanone with ethyl formate, a much higher yield of the... Problem 60AP: Ethyl dimethylacetoacetate reacts instantly at room temperature when treated with ethoxide ion to... Problem 61AP Problem 62AP Problem 63AP: The so-called Wieland-Miescher ketone is a valuable starting material used in the synthesis of... Problem 64AP Problem 65AP Problem 66AP Problem 67AP: What condensation products would you expect to obtain by treatment of the following substances with... Problem 68AP: The following reactions are unlikely to provide the indicated product in high yield. What is wrong... Problem 69AP: Fill in the missing reagents a-h in the following scheme: Problem 70AP Problem 71AP Problem 72AP Problem 73AP Problem 35MP: Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that...
Related questions
Explain this Organic Synthesis with Enolates.
Transcribed Image Text: olla or
H + Me
2
3
MeO
EtO
4
EtOH, NaOH
reflux, 1 h
Me
MeO
NaOH
-H₂O
EtO
MeO
5
Me
Definition Definition Branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups.
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