NaF ? Br DMSO a. identify the type of alkyl halide: b. identify the type of nucleophile/base: c. predict the anticipated mechanism(s): d. predict the major organic product by drawing the appropriate mechanism:
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- . For the following reaction: Br to Na -OH + ? a. identify the type of alkyl halide: b. identify the type of nucleophile/base: c. predict the anticipated mechanism(s): d. predict the major organic product by drawing the appropriate mechanism: . For the following reaction: Br -OH ? a. identify the type of alkyl halide: b. identify the type of nucleophile/base: c. predict the anticipated mechanism(s): d. predict the major elimination product by drawing the appropriate mechanism:1. please answer a and b8) Identify the nucleophile and electrophile in each reaction. А. H. O.. CI CI B.
- . Base . The imol 1. The forme e. Bas perfo In 1 Orav cta 1. Steric hindrance is the unfavorable electron-electron repulsion that results when bonds are forced too close to each other. a. Draw the SN2 mechanism using curved arrows for the reaction of bromoethane with Nu:-. siz b. Draw the SN2 mechanism using curved arrows for the reaction of 2-bromopropane with Nu:. vtisizvod c. Given that steric hindrance is unfavorable, predict whether the SN2 reaction of bromoethane or 2- bromopropane would be faster. d. Determine in general the order of reactivity of all alkyl halides in an SN2 reaction (methyl, 1º, etc.)Match each step with the description that best fits it. a)proton transfer b)nucleophilic attack c)loss of leaving group d)carbocation rearrangementA. Predict the major product of the reaction. CI Ph (РСС) OH CH,Cl2 B. Draw a detailed arrow-pushing mechanism for the transformation, accounting for stereochemistry, if necessary.
- final product. b) Draw the correct first step and complete the mechanism, showing the structure of the HO: H. H. НО-Н H. H. .. reaction. H. H a) Explain why the following mechanism is not plausible for the first step of this 2. Consider the following reaction:Draw the full electron pushing mechanism for the reaction depicted including ALL intermediates (with lone pairs and formal charges). Clearly label the electrophile and nucleophile in each step where appropriate.7. Devise a synthesis of each compound from the given starting material. You may use any needed organic or inorganic reagents. More than one step may be required. Me OH ...Br ??? Eto Me ☑OH Me OH Z ??? ...Br Me OH ....OMe
- 027 In Part 1 add the curved arrows to the nucleophilic acyl substitution reaction mechanism. In Part 2, answer the multiple-choice question about the reaction in Part 1. Part 1 4 See Periodic Table O See Hint :0: :Br: Add the missing curved arrow notation. S CI Br Part 2 Which statement is most correct regarding the equilibrium for the above reaction? Choose one: O The equilibrium favors the right (i.e., Kea > 1) because acetate is a better leaving group than bromide. O The equilibrium favors the right (i.e., Kea > 1) because bromide is a better leaving group than acetate. O The equilibrium favors the left (i.e., Keq« 1) because acetate is a better leaving group than bromide. O The equilibrium favors the left (i.e., Keg 1) because bromide is a better leaving group than acetate. +Predict the major organic product of the given reaction. Select Draw Rings More 1. NaOEt/ETOH 2. CH3CH2CH2Br 3. dilute NaOH/heat 4. H3O* 5. Нeat d orrow mechanism for the scheme by adding any missing atoms, bonds, charges,Synthesize each compound from toluene (CgH,CH3) and any other organic or inorganic reagents. a. CeHsCH2OC(CHa O,N H2N. b. CgH;CHO d. HOOC- -NO2 f. HO. -COOH CHO C. е. g. Br