Monochlorobenzene (M) is produced commercially by the direct catalytic chlorination of benzene (B) at 50.0 °C and 140.0 kPa absolute. In the process, dichlorobenzene (D) is generated as a co-product: CH6 + Cl2- CgH;CI + HCI CSH5CI + Cl2 - CsHạCl2 + HCl Liquid and gas streams leave the reactor. The liquid contains 39.2 wt% M, 32.6 % D, and the remainder unreacted B. The gas, which is sent to a treatment facility, contains 92.0 %(v/v) HCl and 8 % unreacted chlorine. Assume ideal-gas behavior.
Monochlorobenzene (M) is produced commercially by the direct catalytic chlorination of benzene (B) at 50.0 °C and 140.0 kPa absolute. In the process, dichlorobenzene (D) is generated as a co-product: CH6 + Cl2- CgH;CI + HCI CSH5CI + Cl2 - CsHạCl2 + HCl Liquid and gas streams leave the reactor. The liquid contains 39.2 wt% M, 32.6 % D, and the remainder unreacted B. The gas, which is sent to a treatment facility, contains 92.0 %(v/v) HCl and 8 % unreacted chlorine. Assume ideal-gas behavior.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:Monochlorobenzene (M) is produced commercially by the direct catalytic chlorination of benzene (B) at 50.0 °C and 140.0 kPa
absolute. In the process, dichlorobenzene (D) is generated as a co-product:
CH6 + Cl2- CgH;CI + HCI
CGH5CI + Cl2 – C&H4CI2 + HCI
Liquid and gas streams leave the reactor. The liquid contains 39.2 wt% M, 32.6 % D, and the remainder unreacted B. The gas, which is
sent to a treatment facility, contains 92.0 %(v/v) HCl and 8 % unreacted chlorine. Assume ideal-gas behavior.
Volume of Gas
Check stoichiometry and gas behavior.
What volume of gas leaves the reactor (m³) per kg B fed?
i
! m3
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