Molecules can rotate as rigid bodies. The spectrum of a quantum rotor is given by the eigenvalues of the Hamiltonian L2 = H and (H) = E = J(J+1)h² 2M, R 21 where M, is the reduced mass of the nuclei and Ro their equilibrium separation. There exists in nature a particle known as the muon. It is just a heavy electron with a mass m, = 207me. It decays in 10-º seconds. Suppose there exists a molecule analogous to H, (two protons + 1 electron), but with the electron replaced by a muon:
Molecules can rotate as rigid bodies. The spectrum of a quantum rotor is given by the eigenvalues of the Hamiltonian L2 = H and (H) = E = J(J+1)h² 2M, R 21 where M, is the reduced mass of the nuclei and Ro their equilibrium separation. There exists in nature a particle known as the muon. It is just a heavy electron with a mass m, = 207me. It decays in 10-º seconds. Suppose there exists a molecule analogous to H, (two protons + 1 electron), but with the electron replaced by a muon:
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QM 6.3.
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Transcribed Image Text:Molecules can rotate as rigid bodies. The spectrum of a quantum rotor is given by the eigenvalues of the
Hamiltonian
J(J+1)h?
2M, R
L?
H =
and (H) = E =
21
where M, is the reduced mass of the nuclei and Ro their equilibrium separation. There exists in nature a
particle known as the muon. It is just a heavy electron with a mass m, = 207me. It decays in 10-6 seconds.
Suppose there exists a molecule analogous to H (two protons + 1 electron), but with the electron replaced
by a muon:
(a) Find the equilibrium separation of the nuclei (Ro) in such a molecule.
(b) If a rotational state is excited, estimate the wavelength of the emitted radiation in the transition to the
ground state.
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