Minimum-boiling-point azeotropes Initial Composition Experimental Result To left of azeotrope Azeotrope distills first, pure A second Not separable Azeotrope To right of azeotrope Azeotrope distills first, pure B second Махітит-boiling-point azeotropes Initial Composition Experimental Result To left of azeotrope Azeotrope To right of azeotrope Pure A distills first, azeotrope second Not separable Pure B distills first, azeotrope second

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Construct an approximate boiling-point-composition diagram for an acetone– chloroform system, which forms a maximum boiling azeotrope (Table 15.4). Describe the behavior on distillation of a mixture that is initially rich in acetone (90%), and then describe the behavior of a mixture that is initially rich in chloroform (90%).

Minimum-boiling-point azeotropes
Initial Composition
Experimental Result
To left of azeotrope
Azeotrope distills first, pure A second
Not separable
Azeotrope
To right of azeotrope
Azeotrope distills first, pure B second
Махітит-boiling-point azeotropes
Initial Composition
Experimental Result
To left of azeotrope
Azeotrope
To right of azeotrope
Pure A distills first, azeotrope second
Not separable
Pure B distills first, azeotrope second
Transcribed Image Text:Minimum-boiling-point azeotropes Initial Composition Experimental Result To left of azeotrope Azeotrope distills first, pure A second Not separable Azeotrope To right of azeotrope Azeotrope distills first, pure B second Махітит-boiling-point azeotropes Initial Composition Experimental Result To left of azeotrope Azeotrope To right of azeotrope Pure A distills first, azeotrope second Not separable Pure B distills first, azeotrope second
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