Methanol (CH3OH) is often used as a fuel in high-performance engines in race cars. Using the data in the following table compare the standard enthalpy of combustion per gram of methanol with the enthalpy of combustion per gram of gasoline. Gasoline is actually a mixture of compounds, but assume for this problem that gasoline is pure liquid octane (C8H18).
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
- Methanol (CH3OH) is often used as a fuel in high-performance engines in race cars. Using the data in the following table compare the standard enthalpy of combustion per gram of methanol with the enthalpy of combustion per gram of gasoline. Gasoline is actually a mixture of compounds, but assume for this problem that gasoline is pure liquid octane (C8H18).
|
Compound |
ΔHºF |
|
CH3OH |
-239 kJ/mol |
|
C8H18 |
-269 kJ/mol |
|
H2O |
-286 kJ/mol |
|
CO2 |
-394 kJ/mol |
|
CO |
-111 kJ/mol |
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