Mass of solute? Mass of solvent? Molality of the solution? Molar mass of the solute? % error of the MM of unknown solute? Thank you!

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter4: Least-squares And Calibration Methods
Section: Chapter Questions
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Kindly answer the following with proper sig figs and check the data below. Looking for: Mass of solute? Mass of solvent? Molality of the solution? Molar mass of the solute? % error of the MM of unknown solute? Thank you!
Time (sec)
0
15
30
405
450
465
480
495
510
525
540
345
360
375
390
420
435
120
135
150
165
180
210
225
240
255
270
285
300
315
330
45
60
75
90
105
195
Co
Temperature (°C)
100.0
98.0
mass of container+sample,g
mass of container, g
Unknown Solute
mass of container+sample,g
mass of container, g
Lauric acid
Benzophenone
Para-dichlorobenzene
Stearic acid
75.0
75.0
75.0
75.0
75.0
75.0
76.0
76.0
76.0
76.0
93.0
88.0
85.0
82.0
80.0
78.0
77.0
76.0
76.0
76.0
76.0
76.0
76.0
76.0
76.0
75.5
75.5
75.5
75.5
75.5
75.5
75.5
75.5
75.5
75.0
Appearance.
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
Liquid
43.8
49.0⁰
53.1b
69.4
Liquid
Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Colld-Liquid
olid-Liquid
olid-Liquid
olid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Table 3b.4. Data on the determination of the molecular mass of the unknown solute.
Parameter
Unknown Solvent regad
Table 3b.5. Literature values for the identification of the unknown B.
Compound
Melting Point", "C
10092-
Time (sec)
555
570
585
600
615
630
645
660
675
690
705
720
735
750
765
780
795
810
825
840
855
870
885
900
Temperature (°C)
74.5
74.5
74.5
74.5
74.5
74.0
74.0
74.0
73.5
73.5
73.5
73.5
73.5
73.5
71.0
69.0
65.0
63.0
60.0
tulog nwordinu!
58.0
54.0
51.0
49.0
45.0
Value
20.05
18.03
1.53
1.32
b3.9
Appearance
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid-Liquid
Solid
Solid
Solid
Solid
Solid
Solid
Solid
Solid
Solid
Solid
O.ISL
Freezing point depression constant (kr), °C-kg-mol.¹
0.88
0.33
0.20
9.8⁰
7.10⁰
4.27 o nousV18200 E.de sidst
REGE
Naphthalene
3.
Table 30.6. Literature values for the identification of the unknown A.
Compound
Chemical Formula
Sodium chloride
Benzene
Benzoic acid
Diphenylaminetto
80.2
where:
NaCl
C6H6
C₂H₂O₂
C₁₂H₁N
F
711 ==
Molar mass, g'mol 1
58.44
78.108
hog
from the freezin
T-T
ky
122.118
169.208
6.9⁰
T%= freezing point of the pure solvent (use the experimental value)
Tr= freezing point of solution
k = freezing point depression constant of the solvent
m = molality of the solution
Melting Point", "C
801
5.5
122.3
53
on in
3b-3)
Transcribed Image Text:Time (sec) 0 15 30 405 450 465 480 495 510 525 540 345 360 375 390 420 435 120 135 150 165 180 210 225 240 255 270 285 300 315 330 45 60 75 90 105 195 Co Temperature (°C) 100.0 98.0 mass of container+sample,g mass of container, g Unknown Solute mass of container+sample,g mass of container, g Lauric acid Benzophenone Para-dichlorobenzene Stearic acid 75.0 75.0 75.0 75.0 75.0 75.0 76.0 76.0 76.0 76.0 93.0 88.0 85.0 82.0 80.0 78.0 77.0 76.0 76.0 76.0 76.0 76.0 76.0 76.0 76.0 75.5 75.5 75.5 75.5 75.5 75.5 75.5 75.5 75.5 75.0 Appearance. Liquid Liquid Liquid Liquid Liquid Liquid Liquid 43.8 49.0⁰ 53.1b 69.4 Liquid Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Colld-Liquid olid-Liquid olid-Liquid olid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Table 3b.4. Data on the determination of the molecular mass of the unknown solute. Parameter Unknown Solvent regad Table 3b.5. Literature values for the identification of the unknown B. Compound Melting Point", "C 10092- Time (sec) 555 570 585 600 615 630 645 660 675 690 705 720 735 750 765 780 795 810 825 840 855 870 885 900 Temperature (°C) 74.5 74.5 74.5 74.5 74.5 74.0 74.0 74.0 73.5 73.5 73.5 73.5 73.5 73.5 71.0 69.0 65.0 63.0 60.0 tulog nwordinu! 58.0 54.0 51.0 49.0 45.0 Value 20.05 18.03 1.53 1.32 b3.9 Appearance Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid-Liquid Solid Solid Solid Solid Solid Solid Solid Solid Solid Solid O.ISL Freezing point depression constant (kr), °C-kg-mol.¹ 0.88 0.33 0.20 9.8⁰ 7.10⁰ 4.27 o nousV18200 E.de sidst REGE Naphthalene 3. Table 30.6. Literature values for the identification of the unknown A. Compound Chemical Formula Sodium chloride Benzene Benzoic acid Diphenylaminetto 80.2 where: NaCl C6H6 C₂H₂O₂ C₁₂H₁N F 711 == Molar mass, g'mol 1 58.44 78.108 hog from the freezin T-T ky 122.118 169.208 6.9⁰ T%= freezing point of the pure solvent (use the experimental value) Tr= freezing point of solution k = freezing point depression constant of the solvent m = molality of the solution Melting Point", "C 801 5.5 122.3 53 on in 3b-3)
Table 3b.2. Determination of the melting point range, experimental melting point and possible identity of unknowns A and B.
Unknown A
120.5 °C -123.0 °C
Unknown B
78.0 °C- 81.0 °C
79.5°C
Napthalene
0.9%
Parameters
Melting Point Range
Experimental Melting Point
121.8 °C
Benzoic acid
0.4%
Possible Identity
Percent Error, % (Melting Point)
Table 3b.3. Data on the determination of the molecular mass of the unknown coluto
Transcribed Image Text:Table 3b.2. Determination of the melting point range, experimental melting point and possible identity of unknowns A and B. Unknown A 120.5 °C -123.0 °C Unknown B 78.0 °C- 81.0 °C 79.5°C Napthalene 0.9% Parameters Melting Point Range Experimental Melting Point 121.8 °C Benzoic acid 0.4% Possible Identity Percent Error, % (Melting Point) Table 3b.3. Data on the determination of the molecular mass of the unknown coluto
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