LOCH CH₂O LOCH ZnCl₂ 1. HOH HOH HO 2. HO H OH H Glucose (open chain form) a = Electrophilic addition b = E2 Elimination c = SN1 Nucleophilic substitution HOH trace of acid HO HOT HO H OH H OH H₂O b-D-Glucopyranose d = SN2 Nucleophilic substitution e= Electrophilic aromatic substitution f = Carbonyl nucleophilic addn g = Nucleophilic subs at carbonyl(acyl Xfer) h = Conjugate (nucleophilic) addn Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a- i for your answers. 1. 2.

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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CH3O.
LOCH3
CH3O.
OCH3
ZnCl2
H₂O
1.
HO
CH3
HOH
HOHI
HO
2.
HO
H
H
OH
H
HOH
HO
trace of acid
HOT
HO
H
H
OH
H
Glucose (open chain form)
a = Electrophilic addition
b = E2 Elimination
c = SN1 Nucleophilic substitution
-OH
b-D-Glucopyranose
d = SN2 Nucleophilic substitution
e Electrophilic aromatic substitution
f = Carbonyl nucleophilic addn
g
Nucleophilic subs at carbonyl(acyl Xfer)
h = Conjugate (nucleophilic) addn
Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers.
1.
☐ ☐
2.
Transcribed Image Text:CH3O. LOCH3 CH3O. OCH3 ZnCl2 H₂O 1. HO CH3 HOH HOHI HO 2. HO H H OH H HOH HO trace of acid HOT HO H H OH H Glucose (open chain form) a = Electrophilic addition b = E2 Elimination c = SN1 Nucleophilic substitution -OH b-D-Glucopyranose d = SN2 Nucleophilic substitution e Electrophilic aromatic substitution f = Carbonyl nucleophilic addn g Nucleophilic subs at carbonyl(acyl Xfer) h = Conjugate (nucleophilic) addn Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. 1. ☐ ☐ 2.
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