**Learning Target 16****Criteria for Satisfactory Score:**- Reactants, products, and reagents that complete a reaction scheme must specify compounds, not generic categories.- Reagents and structures must be valid Lewis structures.**Tasks:**- Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below.**Reaction Sequences:**1. **Reaction 1:** - Starting compound: - An alcohol with a branched chain, depicted as HO-. - Reagents: - 1. PBr₃ - 2. Mg, dry ether - 3. CH₃CH₂C(O)CH₃ - 4. H₃O⁺ (acid work-up) - [Arrow indicating reaction progress]2. **Reaction 2:** - Starting compound: - Phenol derivative with OH group on a benzene ring. - Reagents: - 1. MsCl, pyridine - 2. CH₃CH₂SH, acetone - [Arrow indicating reaction progress]3. **Reaction 3:** - Starting compound: - A ketone with a benzene ring. - Reagents: - 1. LiAlH₄ - 2. H₃O⁺ - 3. conc. H₂SO₄, heat - [Arrow indicating reaction progress]4. **Reaction 4:** - Reaction of a cyclic alkene: - Reagent: diluted H₂SO₄ - Products: - Two cyclic alcohols, both with OH groups in racemic forms (a mixture of stereoisomers).5. **Figure 14: Reactions:** - Transformation of a cyclohexene derivative into a diol. - Starting compound: - A cyclohexene structure. - Final product: - Cyclohexane with two OH groups in a racemic mixture.This educational content outlines specific organic chemistry reactions, focusing on completing reaction schemes using concrete compounds and valid Lewis structures.

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Learning Target 16 Criteria for satisfactory score Reactants, products, and reagents that complete a reaction scheme must specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. Tasks Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. 1. PBr3 2. Mg, dry ether 3. CH3CH2C(O)CH3 4. H3O* (acid work-up) 1. MSCI, pyridine 2. CH3CH2SH, acetone OH 1. LIAIH4 2. H3O* 3. conc. H2SO4, heat diluted H2SO4 "OH- OH HO" HO OH racemic mixture Figure 14: Reactions

Learning Target 16 Criteria for satisfactory score Reactants, products, and reagents that complete a reaction scheme must specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. Tasks Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. 1. PBr3 2. Mg, dry ether 3. CH3CH2C(O)CH3 4. H3O* (acid work-up) 1. MSCI, pyridine 2. CH3CH2SH, acetone OH 1. LIAIH4 2. H3O* 3. conc. H2SO4, heat diluted H2SO4 "OH- OH HO" HO OH racemic mixture Figure 14: Reactions

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Starting materials Br Reagents OH 1 H3C OH 2 Br 6 Br 7 OH OH TOH OH 8 5 H a Mg / dry ether e Aqueous H2SO4 at reflux i KMnO4 / H3O+ b 1. CO2 2. acidic workup of Conc. HCI or HCI (gas) j Na2CrO4 / aqueous H2SO4 C NaCN/THF or DMF g PBr3 K 1. BH3/THF 2. H₂O2/aq. NaOH d NaCN/dil. aqueous H2SO4 h KOH alcohol |
part 2 [References] Draw the final organic product of this series of reactions. 1. CH;CH2COCI, AICI3 2. Br2, CH3CO2H 3. K* tBuo 4. OsO, then NaHSO3 5. H2Cro4 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not draw organic or inorganic by-products. C P. opy aste
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QUESTION 2 OBJECTIVES (2 part) 0 Understand how chemical structure affects electrophilicity and nucleophilicity. • Understand acid/base chemistry and apply the principles of ARIO. 1. A. Understand the interplay between resonance effects and leaving group ability. Why won't the following reactions work as shown? What are the issues with the reactions below? Explain each in 1-2 sentences. OH 亠从 ONa B. OH NH2 I 一人 5
9 [Review Topics] Draw the organic product(s) of the following reaction. 288 F4 V ÿ981 O % 5 You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right e T JUL 1 9 corner. . Separate multiple products using the + sign from the drop-down menu. B 6 OH II... + Fo Y ногон MacBook Air H tv Nall & 7 N 80 F7 Y C p-toluenesulfonic acid benzene, 80° * 00 Sn [F 8 K ChemDoodle DII FB I M [References] ♫AD ( 9 K DD FO O V O L 人口 O F10 P V ( F11 + { = [ Previous (211) F12 11 ? F Next> Save a 1 del
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Suppose you are given the starting molecule shown below. For each of the cases listed below, list the reaction conditions and reagents that would give that product, and give a brief explanation of why ONLY the specified product would be formed under the conditions you chose. Make product alcohol with OH group at carbon 1. Make product alcohol with OH group at carbon 2. Make product alcohol with OH group at carbon 3. а. b. 3 2 C.
Criteria for satisfactory score Reactants, products, and reagents that complete a reaction scheme must specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. Tasks Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. 1. t-BUOK, heat 2. Br2 (1 equiv) methanol (solvent) Br 1. O3 2. Me2S 1. Hg(OAc)2, H2O 2. NABH4
What is the mechanism to get from the reactant to the products