of OH Starting materials 1 Br H,C OH 2 Br 6 Reagents a Mg / dry ether b 1. CO2 2. acidic workup c NaCN/THF or DMF Br 7 3 LOH OH e Aqueous H2SO4 at reflux f Conc. HCI or HCI (gas) g PBr d NaCN/ dil. aqueous H2SO4 h KOH/alcohol | 4 -OH 8 I KMnO/H₂O* I 5 H Na₂ CrO4 / aqueous H₂SO4 k 1. BH3/THF 2. H2O2/aq. NaOH
of OH Starting materials 1 Br H,C OH 2 Br 6 Reagents a Mg / dry ether b 1. CO2 2. acidic workup c NaCN/THF or DMF Br 7 3 LOH OH e Aqueous H2SO4 at reflux f Conc. HCI or HCI (gas) g PBr d NaCN/ dil. aqueous H2SO4 h KOH/alcohol | 4 -OH 8 I KMnO/H₂O* I 5 H Na₂ CrO4 / aqueous H₂SO4 k 1. BH3/THF 2. H2O2/aq. NaOH
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:Starting materials
Br
Reagents
OH
1
H3C
OH
2
Br
6
Br
7
OH
OH
TOH
OH
8
5
H
a Mg / dry ether
e Aqueous H2SO4 at reflux
i KMnO4 / H3O+
b 1. CO2
2. acidic workup
of Conc. HCI or HCI (gas)
j Na2CrO4 / aqueous H2SO4
C NaCN/THF or DMF
g PBr3
K 1. BH3/THF 2. H₂O2/aq. NaOH
d NaCN/dil. aqueous H2SO4
h KOH alcohol
|

Transcribed Image Text:OH
Starting materials
Br
Reagents
1
OH
H3C
2
རྨ.
Br
Br
7
3
OH
OH
HO+
8
5
H
a Mg / dry ether
e Aqueous H2SO4 at reflux
i KMnO4 / H3O+
b 1. CO2 2. acidic workup
of Conc. HCI or HCI (gas)
j Na2 CrO 4 / aqueous H2SO4
c NaCN/THF or DMF
g PBr3
k 1. BH3/THF 2. H₂O₂/aq. NaOH
d NaCN/dil. aqueous H2SO4
h KOH/alcohol
|
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