Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as follows: 2A + В - 2C (all gases) The method of initial rates is used to determine the rate law for this reaction. JA], initial 0.0100 M 0.0200 M 0.0100 M |B], initial 0.0400 M 0.0200 M 0.0200 M Rate (M/sec) 7.5 x 10* 3.0 x 10² 7.5 x 10* Experiment 2 3 The following four mechanisms can be considered along with the data given above. a) A + D + C ½B + D → C fast equilibrium slow b) А + A + В - D с + с slow fast D c) A + A + D ½B D + D fast equilibrium slow C + D d) A + A B + D + C slow fast equilibrium
Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as follows: 2A + В - 2C (all gases) The method of initial rates is used to determine the rate law for this reaction. JA], initial 0.0100 M 0.0200 M 0.0100 M |B], initial 0.0400 M 0.0200 M 0.0200 M Rate (M/sec) 7.5 x 10* 3.0 x 10² 7.5 x 10* Experiment 2 3 The following four mechanisms can be considered along with the data given above. a) A + D + C ½B + D → C fast equilibrium slow b) А + A + В - D с + с slow fast D c) A + A + D ½B D + D fast equilibrium slow C + D d) A + A B + D + C slow fast equilibrium
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as
follows:
2A + В - 2C
(all gases)
The method of initial rates is used to determine the rate law for this reaction.
JA], initial
0.0100 M
0.0200 M
0.0100 M
|B], initial
0.0400 M
0.0200 M
0.0200 M
Rate (M/sec)
7.5 x 10*
3.0 x 10²
7.5 x 10*
Experiment
2
3
The following four mechanisms can be considered along with the data given above.
a) A + D + C
½B + D → C
fast equilibrium
slow
b) А + A + В - D
с + с
slow
fast
D
c) A + A
+ D
½B
D + D
fast equilibrium
slow
C + D
d) A + A
B + D + C
slow
fast equilibrium](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4f7442e5-ed1a-4154-ba5d-4813abad6cff%2F965896c5-2334-4ebc-aacd-b6eb924ecb04%2Fcut5i6o.png&w=3840&q=75)
Transcribed Image Text:Kinetics. The kinetics of a certain reaction is studied. The balanced reaction is expressed symbolically as
follows:
2A + В - 2C
(all gases)
The method of initial rates is used to determine the rate law for this reaction.
JA], initial
0.0100 M
0.0200 M
0.0100 M
|B], initial
0.0400 M
0.0200 M
0.0200 M
Rate (M/sec)
7.5 x 10*
3.0 x 10²
7.5 x 10*
Experiment
2
3
The following four mechanisms can be considered along with the data given above.
a) A + D + C
½B + D → C
fast equilibrium
slow
b) А + A + В - D
с + с
slow
fast
D
c) A + A
+ D
½B
D + D
fast equilibrium
slow
C + D
d) A + A
B + D + C
slow
fast equilibrium

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