Ketones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give alcohols, as shown in the following example: R, OH C. R2 1. HC=C: Na* `R2 2. H30* HC When this compound reacts with sodium acetylide, CH3 H3C a: Is the product chiral?| b: Assuming that the reaction takes place with equal likelihood from both Re and Si faces of the carbonyl group, is the product optically active? | R.
Ketones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give alcohols, as shown in the following example: R, OH C. R2 1. HC=C: Na* `R2 2. H30* HC When this compound reacts with sodium acetylide, CH3 H3C a: Is the product chiral?| b: Assuming that the reaction takes place with equal likelihood from both Re and Si faces of the carbonyl group, is the product optically active? | R.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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a: Is the product chiral? _____
b: Assuming that the reaction takes place with equal likelihood from both Re and Si faces of the carbonyl group, is the product optically active? ____
Transcribed Image Text:Ketones and aldehydes react with sodium acetylide (the sodium salt of acetylene) to give alcohols, as shown in the following example:
R, OH
C.
R2
1. НС—с: Na"
R1
`R2
2. Hзо*
HC
When this compound reacts with sodium acetylide,
CH3
H3C
a: Is the product chiral?
b: Assuming that the reaction takes place with equal likelihood from both Re and Si faces of the carbonyl group, is the product optically active?
Transcribed Image Text:When this compound reacts with sodium acetylide,
a: Is the product chiral?|
b: Assuming that the reaction takes place with equal likelihood from both .
and Si faces of the carbonyl group, is the product optically active?
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