The following structures are OH O identical O diastereomers NHCH3 Oenantiomers O constitutional (structural) isomers ****** OH NHCH3

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Title: Understanding Stereochemistry in Organic Compounds**

**Topic: Identifying Relationships Between Chemical Structures**

The following question involves analyzing organic compounds to determine their stereochemistry. Examine the two structures provided and determine their relationship:

**Structures Provided:**
1. The first structure:
   - Contains a benzene ring (hexagon with alternating double bonds).
   - Attached to the benzene ring is a carbon with two substituents: an -OH group (hydroxyl group) and an -NHCH₃ group (methylamine group).
   - The hydroxyl group is attached with a solid wedge bond indicating the position relative to the plane of the ring.

2. The second structure:
   - Similar to the first structure with the same substituents (benzene ring, hydroxyl group, and methylamine group).
   - The hydroxyl group is attached with a dashed wedge bond indicating the opposite position relative to the plane of the ring compared to the first structure.

**Question:**
These structures are:
- Identical
- Diastereomers
- Enantiomers
- Constitutional (structural) isomers

**Explanation:**

The provided structures show two organic molecules with specific configurations around a chiral center. The distinction in their three-dimensional arrangements is key to determining their stereochemical relationship:
1. **Identical:** If the molecules are superimposable on each other in every aspect.
2. **Diastereomers:** Stereoisomers that are not mirror images of each other.
3. **Enantiomers:** Non-superimposable mirror images.
4. **Constitutional (structural) isomers:** Compounds with the same molecular formula but different connectivity of atoms.

Given the configurations provided:
- The molecules have opposite configurations at the chiral center (the carbon attached to both the -OH and -NHCH₃).
- They are non-superimposable mirror images of each other. Therefore, they are enantiomers.

**Conclusion:**
The correct answer is: **Enantiomers**
Transcribed Image Text:**Title: Understanding Stereochemistry in Organic Compounds** **Topic: Identifying Relationships Between Chemical Structures** The following question involves analyzing organic compounds to determine their stereochemistry. Examine the two structures provided and determine their relationship: **Structures Provided:** 1. The first structure: - Contains a benzene ring (hexagon with alternating double bonds). - Attached to the benzene ring is a carbon with two substituents: an -OH group (hydroxyl group) and an -NHCH₃ group (methylamine group). - The hydroxyl group is attached with a solid wedge bond indicating the position relative to the plane of the ring. 2. The second structure: - Similar to the first structure with the same substituents (benzene ring, hydroxyl group, and methylamine group). - The hydroxyl group is attached with a dashed wedge bond indicating the opposite position relative to the plane of the ring compared to the first structure. **Question:** These structures are: - Identical - Diastereomers - Enantiomers - Constitutional (structural) isomers **Explanation:** The provided structures show two organic molecules with specific configurations around a chiral center. The distinction in their three-dimensional arrangements is key to determining their stereochemical relationship: 1. **Identical:** If the molecules are superimposable on each other in every aspect. 2. **Diastereomers:** Stereoisomers that are not mirror images of each other. 3. **Enantiomers:** Non-superimposable mirror images. 4. **Constitutional (structural) isomers:** Compounds with the same molecular formula but different connectivity of atoms. Given the configurations provided: - The molecules have opposite configurations at the chiral center (the carbon attached to both the -OH and -NHCH₃). - They are non-superimposable mirror images of each other. Therefore, they are enantiomers. **Conclusion:** The correct answer is: **Enantiomers**
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Alkanes and Cycloalkanes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY