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The following structures are OH O identical O diastereomers NHCH3 Oenantiomers O constitutional (structural) isomers ****** OH NHCH3

The following structures are OH O identical O diastereomers NHCH3 Oenantiomers O constitutional (structural) isomers ****** OH NHCH3

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Title: Understanding Stereochemistry in Organic Compounds** **Topic: Identifying Relationships Between Chemical Structures** The following question involves analyzing organic compounds to determine their stereochemistry. Examine the two structures provided and determine their relationship: **Structures Provided:** 1. The first structure: - Contains a benzene ring (hexagon with alternating double bonds). - Attached to the benzene ring is a carbon with two substituents: an -OH group (hydroxyl group) and an -NHCH₃ group (methylamine group). - The hydroxyl group is attached with a solid wedge bond indicating the position relative to the plane of the ring. 2. The second structure: - Similar to the first structure with the same substituents (benzene ring, hydroxyl group, and methylamine group). - The hydroxyl group is attached with a dashed wedge bond indicating the opposite position relative to the plane of the ring compared to the first structure. **Question:** These structures are: - Identical - Diastereomers - Enantiomers - Constitutional (structural) isomers **Explanation:** The provided structures show two organic molecules with specific configurations around a chiral center. The distinction in their three-dimensional arrangements is key to determining their stereochemical relationship: 1. **Identical:** If the molecules are superimposable on each other in every aspect. 2. **Diastereomers:** Stereoisomers that are not mirror images of each other. 3. **Enantiomers:** Non-superimposable mirror images. 4. **Constitutional (structural) isomers:** Compounds with the same molecular formula but different connectivity of atoms. Given the configurations provided: - The molecules have opposite configurations at the chiral center (the carbon attached to both the -OH and -NHCH₃). - They are non-superimposable mirror images of each other. Therefore, they are enantiomers. **Conclusion:** The correct answer is: **Enantiomers**
Transcribed Image Text:**Title: Understanding Stereochemistry in Organic Compounds** **Topic: Identifying Relationships Between Chemical Structures** The following question involves analyzing organic compounds to determine their stereochemistry. Examine the two structures provided and determine their relationship: **Structures Provided:** 1. The first structure: - Contains a benzene ring (hexagon with alternating double bonds). - Attached to the benzene ring is a carbon with two substituents: an -OH group (hydroxyl group) and an -NHCH₃ group (methylamine group). - The hydroxyl group is attached with a solid wedge bond indicating the position relative to the plane of the ring. 2. The second structure: - Similar to the first structure with the same substituents (benzene ring, hydroxyl group, and methylamine group). - The hydroxyl group is attached with a dashed wedge bond indicating the opposite position relative to the plane of the ring compared to the first structure. **Question:** These structures are: - Identical - Diastereomers - Enantiomers - Constitutional (structural) isomers **Explanation:** The provided structures show two organic molecules with specific configurations around a chiral center. The distinction in their three-dimensional arrangements is key to determining their stereochemical relationship: 1. **Identical:** If the molecules are superimposable on each other in every aspect. 2. **Diastereomers:** Stereoisomers that are not mirror images of each other. 3. **Enantiomers:** Non-superimposable mirror images. 4. **Constitutional (structural) isomers:** Compounds with the same molecular formula but different connectivity of atoms. Given the configurations provided: - The molecules have opposite configurations at the chiral center (the carbon attached to both the -OH and -NHCH₃). - They are non-superimposable mirror images of each other. Therefore, they are enantiomers. **Conclusion:** The correct answer is: **Enantiomers**
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