Is NO serving as a catalyst or an intermediate in this reaction? c. If experiments show that during the decomposition of ?2?, ??2 does not accumulate in measurable quantities, does this rule out the proposed mechanism

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.6: Reaction Mechanisms
Problem 2RC: A reaction is believed to occur by the following mechanism: Stepl: 2AI (Fast equilibrium) Step 2: I...
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6. The addition of NO accelerates the decomposition of ?2?, possibly by the
following mechanism:
??(?) + ?2?(?) → ?2
(?) + ??2(?)
2 ??2
(?) → 2 ??(?) + ?2(?)
a. What is the chemical equation for the overall reaction? Show how the
two steps can be added to give the overall equation.
b. Is NO serving as a catalyst or an intermediate in this reaction?
c. If experiments show that during the decomposition of ?2?, ??2 does
not accumulate in measurable quantities, does this rule out the
proposed mechanism

 

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