Iron (III) chloride, FeCl3 is an orange to brown-black solid at room temperature. It is used in drinking water production and sewage water treatment as well as catalyst for several chemical reactions. It is also non-combustible but highly corrosive to metals and tissue when wet. Write the electronic configuration of Iron and Chlorine atoms with Z= 22 and Z = 17 respectively. By referring to the given periodic table, compare the electronegativity and radius i. ii. size between iron and chlorine. iii. Draw the Lewis structure of solid Iron (III) chloride. iv. Using your knowledge of chemistry, determine the type of bonding present in Iron (III) chloride.
Types of Chemical Bonds
The attractive force which has the ability of holding various constituent elements like atoms, ions, molecules, etc. together in different chemical species is termed as a chemical bond. Chemical compounds are dependent on the strength of chemical bonds between its constituents. Stronger the chemical bond, more will be the stability in the chemical compounds. Hence, it can be said that bonding defines the stability of chemical compounds.
Polarizability In Organic Chemistry
Polarizability refers to the ability of an atom/molecule to distort the electron cloud of neighboring species towards itself and the process of distortion of electron cloud is known as polarization.
Coordinate Covalent Bonds
A coordinate covalent bond is also known as a dative bond, which is a type of covalent bond. It is formed between two atoms, where the two electrons required to form the bond come from the same atom resulting in a semi-polar bond. The study of coordinate covalent bond or dative bond is important to know about the special type of bonding that leads to different properties. Since covalent compounds are non-polar whereas coordinate bonds results always in polar compounds due to charge separation.
![1.
Iron (III) chloride, FeCl; is an orange to brown-black solid at room temperature. It is used
in drinking water production and sewage water treatment as well as catalyst for several
chemical reactions. It is also non-combustible but highly corrosive to metals and tissue
when wet.
Write the electronic configuration of Iron and Chlorine atoms with Z= 22 and Z =
17 respectively.
By referring to the given periodic table, compare the electronegativity and radius
i.
ii.
size between iron and chlorine.
Draw the Lewis structure of solid Iron (III) chloride.
Using your knowledge of chemistry, determine the type of bonding present in Iron
(III) chloride.
iii.
iv.
2.
Rasputin, often referred to as “mad monk", was a very powerful figure in the life of
Alexandra, the last Tsarina of Russia. His enemies decided to kill him using a cyanide
compound. Cyanide compounds are deadly poisons. Using a bottle of potassium cyanide,
they attempted to poison a cake and some wine. Rasputin ate the cake and drank the wine
and yet was not harmed. Given the following information :
KCN (s) + acid (aq) → potassium salt (s) + HCN (g)
H-C=N:
K
: С :::
N :
Molecular mass : 27.025 g/mol
Molecular mass : 65.116 g/mol
Tb : 1625 oC
Tm : 634 oC
Solid white powder
Tb : 25.6 oC
Tm : -13.4 oC
Colourless to pale-blue gas
i.
State all types of intra- and inter-molecular bonding exist in both compound. Use
a table to facilitate your answer.
Explain why HCN exist as a gas while KCN exist as a solid at room temperature.
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