Initial concentration (mol-dm) Initial rate (mol-dm-3.s-1) Exp [r] [S2O8 2-1 1 0.080 0.040 12.5 x 106 2 0.040 0.040 6.25 x 106 0.080 0.020 6.25 x 106 4 0.032 0.040 5.00 x 106 5 0.060 0.030 7.00 x 10-6 3.

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2.1 Data in the table below were collected at 25°C for the following reaction:
2 I

(aq) + S2O8
2–
(aq) I2 (aq) + 2 SO4
2-
(aq)

a) Determine the rate law for the reaction.
b) Calculate the rate constant, giving the correct units for k.

Initial concentration (mol-dm)
Initial rate (mol-dm-3.s-1)
Exp
[r]
[S2O8 2-1
1
0.080
0.040
12.5 x 106
2
0.040
0.040
6.25 x 106
0.080
0.020
6.25 x 106
4
0.032
0.040
5.00 x 106
5
0.060
0.030
7.00 x 10-6
3.
Transcribed Image Text:Initial concentration (mol-dm) Initial rate (mol-dm-3.s-1) Exp [r] [S2O8 2-1 1 0.080 0.040 12.5 x 106 2 0.040 0.040 6.25 x 106 0.080 0.020 6.25 x 106 4 0.032 0.040 5.00 x 106 5 0.060 0.030 7.00 x 10-6 3.
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