In the laboratory, hexane has been added to nitrobenzene, and vice versa, until completely miscible solutions are obtained. These tests have been carried out at different temperatures, achieving the following results: x(C6H5NO2) 0,14 0,20 0,25 T 273 280 285 x(C6H5NO2) 0,92 0,90 0,85 If you prepare a mixture of 50 g of hexane and 50 g of nitrobenzene at 290K: a) What is the composition and quantity of each phase? b) To what temperature must the mixture be heated to achieve a single phase? c) If you keep heating up from the previous temperature, you can cause the liquid-vapor transition. Qualitatively represents the appearance of this diagram when the enthalpy of the mixing process is zero and negative. 0,08 260 0,95 0,43 293 0,73 0,60 295 0,60

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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In the laboratory, hexane has been added to nitrobenzene, and vice versa, until completely
miscible solutions are obtained. These tests have been carried out at different temperatures,
achieving the following results:
x(C6H5NO2) 0,08
0,14
0,20
0,25
0,43
0,60
260
273
280
285
293
295
| x(C6H5NO2)
0,95
0,92
0,90
0,85
0,73
0,60
If you prepare a mixture of 50 g of hexane and 50 g of nitrobenzene at 290K:
a) What is the composition and quantity of each phase?
b) To what temperature must the mixture be heated to achieve a
single phase?
c) If you keep heating up from the previous temperature, you can
cause the liquid-vapor transition. Qualitatively represents the appearance of this diagram when
the enthalpy of the mixing process is zero and negative.
Transcribed Image Text:In the laboratory, hexane has been added to nitrobenzene, and vice versa, until completely miscible solutions are obtained. These tests have been carried out at different temperatures, achieving the following results: x(C6H5NO2) 0,08 0,14 0,20 0,25 0,43 0,60 260 273 280 285 293 295 | x(C6H5NO2) 0,95 0,92 0,90 0,85 0,73 0,60 If you prepare a mixture of 50 g of hexane and 50 g of nitrobenzene at 290K: a) What is the composition and quantity of each phase? b) To what temperature must the mixture be heated to achieve a single phase? c) If you keep heating up from the previous temperature, you can cause the liquid-vapor transition. Qualitatively represents the appearance of this diagram when the enthalpy of the mixing process is zero and negative.
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