In the experiment, potassium permanganate is used to oxidize 2-chlorotoluene (o-chlorotoluene) to 2-chlorobenzoic acid (o-chlorobenzoic acid). Permanganate solutions are less hazardous than those containing chromium compounds, which are often carcinogenic. .CH3 СООН 1. KMnO4, H,О, д 2. HСІ, Н,0 `CI `Cl The yield of the reaction observed in the literature (Clarke, H. T.; Taylor, E. R. Org. Synth. 1930, 10, 20) is 76-78 % before recrystallization and 65-67 % after recrystallization.
In the experiment, potassium permanganate is used to oxidize 2-chlorotoluene (o-chlorotoluene) to 2-chlorobenzoic acid (o-chlorobenzoic acid). Permanganate solutions are less hazardous than those containing chromium compounds, which are often carcinogenic. .CH3 СООН 1. KMnO4, H,О, д 2. HСІ, Н,0 `CI `Cl The yield of the reaction observed in the literature (Clarke, H. T.; Taylor, E. R. Org. Synth. 1930, 10, 20) is 76-78 % before recrystallization and 65-67 % after recrystallization.
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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In the experiment, potassium permanganate is used to oxidize 2-chlorotoluene (o-chlorotoluene)
to 2-chlorobenzoic acid (o-chlorobenzoic acid). Draw the step by step mechanism.
Transcribed Image Text:In the experiment, potassium permanganate is used to oxidize 2-chlorotoluene (o-chlorotoluene)
to 2-chlorobenzoic acid (o-chlorobenzoic acid). Permanganate solutions are less hazardous than
those containing chromium compounds, which are often carcinogenic.
.CH3
СООН
1. KMnO4, H,О, д
2. HСІ, Н,0
`CI
`Cl
The yield of the reaction observed in the literature (Clarke, H. T.; Taylor, E. R. Org. Synth. 1930,
10, 20) is 76-78 % before recrystallization and 65-67 % after recrystallization.
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