In the concentration range of 1 to 100 µg/mL P , phosphate suppresses the atomic absorption of Ca in a linear manner. The absorbance levels off, however, between 100 and 300 µg/mL P. Explain. How can this effect be reduced?

In the concentration range of 1 to 100 µg/mL P , phosphate suppresses the atomic absorption of Ca in a linear manner. The absorbance levels off, however, between 100 and 300 µg/mL P. Explain. How can this effect be reduced?

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter9: Atomic Absorption And Atomic Fluorescence Spectrometry

Section: Chapter Questions

Problem 9.18QAP: In the concentration range of 1 to 100 g/mL P, phosphate suppresses the atomic absorption of Ca in a...

See similar textbooks

Related questions

Q: a) Write out what data and information you plan to collect during the experiment of Freezing Point…

A: In the experiment of Freezing Point Depression, the following data and information need to be…

Q: The determination of the relative amounts of carbonates and bicarbonates finds applications in…

A: Step 1: Step 2: Step 3: Step 4:

Q: 6. Calculate the mass of N₂HBr that must be added to 875 mL 0.100 M N₂H4 to make a pH 10.10 buffer…

A: First, we need to calculate the pOH of the solution. The pOH is the negative logarithm (base 10) of…

Q: 34. The reaction 2NO(g) + O2(g) → 2NO₂(g) was studied, and the following data were obtained where…

Q: 10. Nitric acid and nitrous acid are both acids that you would not want to spill on your feet. But…

A: Step 1: Step 2: Step 3: Step 4:

Q: 13.28 Draw all resonance structures of the radical that results from abstraction of a hydrogen atom…

Q: None

A: Bronsted Acid-Base Reaction:In a Bronsted acid-base reaction, the acid donates a proton H+ and…

Q: Calculate the solubility at 25°C of BaCrO4 in pure water and in a 0.0080M BaCl2 solution. Ksp is…

A: Answer:: The solubility of BaCrO4 in pure water is 1.08×10-5 M and in 0.0080 M BaCl2 solution is…

Q: None

A: Step 1:Cyclic alkyne has 8 carbons C8 - oct Triple bond - yne Step 2: Step 3: Step 4:

Q: 7. Complete the drawings below to represent an enantiomer and diastereomer of the compound in the…

A: Step 1: Step 2: Step 3: Step 4:

Q: B. A chemist thinks the following molecule may make an interesting dye for use in the textiles…

Q: Give the answer in scientifi notation to the correct number of significant figures and with correct…

A: First, we need to identify the conversion factors that will allow us to convert from kilometers per…

Q: Chapter Homework 2 Question 10 of 10 (0.1 points) | Question Attempt: 5 of 5 Part: 274 Part 3 of 4…

Q: Show work with explanation needed. Don't give Ai generated solution

A: Step 1: Step 2: Step 3: Step 4:

Q: Calculate the molar conductance at infiniten dilution for K3PO4 when equivalent ionic conductivity…

A: Molar conductance at infinite dilution, often denoted as Λm°, is the conductance of all the ions…

Q: Please correct answer and don't use hand rating

A: Answer 2)Transmission (T) of a blank sample is typically 100% because no sample is present to absorb…

Q: K +2576 pts /3500 © Macmillan Learning G Resources ? Hint Submit Answer Three structural isomers…

A: The three structural isomers of pentane (C₅H₁₂) are:n-Pentane (Pentane):A straight-chain alkane…

Q: None

A: CrO₃ in the presence of sulfuric acid is a strong oxidizing agent, commonly used in the Jones…

Q: Please correct answer and don't use hand rating

Q: Draw four good/useful resonance structures of the following compound: (8 pts)

Q: Determine the order with respect to A and the order with respect to B.

A: The order of a reaction is a term used to describe the relationship between the rate of a chemical…

Q: Which of the following correctly describes subatomic particles? Mass: e− < p+ = n Magnitude of…

A: Approach to solving the question:Concept of subatomic particlesDetailed explanation:

Q: 13.45 What reagents are needed to convert cyclopentene to (a) bromocyclopentane; (b)…

A: a.Cyclopentene undergoes addition reaction with HBr to form bromocyclopentane.b.Cyclopentene…

Q: show the derivation of the half-life equation for a first order reaction from the integrated rate…

Q: None

A: The number of moles of produced depends on the stoichiometric coefficients in the equation, which…

Q: Question Completion Status: QUESTION 1 Name following compounds. Pay attention to spelling. XeCl2…

A: Step 1: CoCl2.2H2O is the chemical formula of Cobalt(II) Chloride dihydrate, a coordination polymer…

Q: 8. The nature of cyclopentadiene (right) was discussed in detail in both lecture and the textbook.…

A: 8.(a) 8.(c)

Q: Please correct answer and don't use hand rating

A: 5 Answer) Reaction Equations and Gibbs Free Energy Changes:Reaction 1: Glucose-1P→Glucose+Pi; ∆G°΄ =…

Q: 7. Given 100.0 mL of a buffer that is 0.50 M in HCIO (Ka = 3.5 X 10%) and 0.40 M in NACIO, what is…

A: First, we need to calculate the moles of HCIO, NACIO and HCl. The number of moles is calculated by…

Q: 6 1 point The amount of heat required to melt 0.02mg of H2O is 12.3J and the amount of heat required…

A: The question explains the mass and heat values involved in water melting. We can divide the domains…

Q: The following scheme shows possible interconversions between alkenes, alkyl halides, alcohols and…

A: Step 1: Step 2: Step 3: Step 4:

Q: For the Lewis acid-base reaction: Draw the skeletal structure of the product(s) for the Lewis…

A: Step 1: Step 2: Step 3: Step 4:

Q: With explanation

A: Step 1: Step 2: Step 3: Step 4:

Q: Please correct answer and don't use hand rating

A: Step 1:Find Unstable Isotopes: In the simulation, you will add or remove neutrons from the elements.…

Q: Find the effective kinetic order for the time course of the drug concentration and the rate…

A: The problem is asking us to determine the effective kinetic order and the rate constant for the…

Q: help please answer in text form with proper workings and explanation for each and every part and…

Q: How much wood could a woodchuck chuck, if a woodchuck could chuck 15.5 kg/min. over an 8 hour…

A: First, we need to convert the rate at which the woodchuck is chucking wood from kilograms per minute…

Q: How how do i find out many protons are found in the nucleus of a boron-11 (11B) atom?

A: In an atom, the nucleus is the central part that contains protons and neutrons. Protons carry a…

Q: Please correct answer and don't use hand rating

A: Molar mass of Na2SO4Sodium (Na): 2×22.99 g/mol=45.98 g/molSulfur (S): 1×32.06 g/mol=32.06…

Q: Please correct answer and don't use hand rating

A: To answer the question about the boiling point of a mixture containing two liquids with different…

Q: write out what data and information you plan to collect during the experiment- denisty of water…

A: The data to be collected in this experiment includes the volume of water measured using both a 10-mL…

Q: None

A: Approach to solving the question: Detailed explanation: Examples: Key references:

Q: Ortho-phenanthroline reacts with ferrous ion to produce a deeply colored complex with a molar…

Q: Construct the expression for the equilibrium constant, Kc, for this reaction. = CaCO3(s) CaO(s) +…

A: Thank you.

Q: Question 7: Calculate the pH of the following buffers (give your answers with 2 decimal places) The…

A: The pH of a solution is a measure of the concentration of hydrogen ions in it. It is calculated…

Q: Consider this organic mechanism: E H H 1 Calculator : OH Click and drag to start drawing a…

A: Step 1: Step 2: Step 3: Step 4:

Q: None

A: Step 1: Step 2: Step 3: Step 4:

Q: What is (are) the reason(s) for the following actions a.) Addition of sulfuric acid to the…

A: Step 1: a) Aspirin is nothing but acetyl salicylic acid and it is prepared by performing acetylation…

Q: help please answer in text form with proper workings and explanation for each and every part and…

A: Step 1: To calculate the concentration in % (w/v) for each standard sugar solution, follow these…

Q: Please correct answer and don't use hand rating

A: In a step-growth polymerization reaction, the number average degree of polymerization (X‾n) can be…

Question

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step by step

Solved in 2 steps

SEE SOLUTION Check out a sample Q&A here

Similar questions

2. What is the concentration (mM) of a solution of tryptophan if the absorbance at 280 nm is 0.850? The cell path length is 1.0 cm and the extinction coefficient is 5500 M-1 cm-1
A solution of copper(II) sulfate is observed to be blue in color. The maximum absorbance is expected to occur in what wavelength range? 500-560 nm (green) 380-435 nm (violet) 610-750 nm (red) 580-595 nm (yellow) 435-480 nm (blue)
. A solution containing the complex formed between two substances has a molar absorptivity of 9.32 X 103 L mol-1 cm-1 at 470 nm. a)What is the absorbance of a 6.24x10-5 M solution of the complex at 470 nm in a 1.00 cm cell? b)What is the percent transmittance of the solution described in (a)? c)What is the molar concentration of the complex in a solution that has the absorbance described in (a) when measured at 470 nm in a 5.00 cm cell . A solution containing the complex formed between two substances has a molar absorptivity of 9.32 X 103 L mol-1 cm-1 at 470 nm. a)What is the absorbance of a 6.24x10-5 M solution of the complex at 470 nm in a 1.00 cm cell? b)What is the percent transmittance of the solution described in (a)? c)What is the molar concentration of the complex in a solution that has the absorbance described in (a) when measured at 470 nm in a 5.00 cm cell
please help with this textbook activity. I need parts A,B,C please
See images below
5
A solution in part C initially contains (4.06x10^-4) molar SCN¯ and (2.960x10^-3) molar Fe3+. This solution was then measured using the colorimeter, and an absorbance of (4.9800x10^-1) was recorded.The constant determined in part A of the experiment was found to be (3.8200x10^3). Using the data provided above, determine the equilibrium concentration of SCN", [SCN]E in this solution. Note: Your answer is assumed to be reduced to the highest power possible. Your Answer: x10 Answer units
A standard solution was put through appropriate dilutions to give the concentrations of iron shown in the table that follows. The iron(II)-1,10-phenanthroline complex was then formed in 25.0-mL aliquots of these solutions, following which each was diluted to 50.0 mL. The following absorbances (1.00-cm cells) were recorded at 510 nm: Calculate the concentration, in ppm, of a sample with an abosrbance of 0.829. Fe(II) concentration (ppm) A510 4.00 0.160 10.0 0.390 16.0 0.630 24.0 0.950 32.0 1.260 40.0 1.580
A solution containing a complex formed between thiourea and Bi (III) has a molar absorptivity of 9.32 × 103 L / cm.mol at 470 nm. Questions: A) What is the absorbance of a 5.67 × 10-5 M solution of the complex at 470 nm in a 1.00 cm cell? B) What is the transmittance of the solution? C) What would the concentration be if we have the same absorbance obtained in (a) at 470 nm in a 2.50 cm cell?
Ligand X forms a complex with both cobalt and copper, each of which has a maximum absorbance at 510 nm and 645 nm, respectively. A 0.256 g sample containing cobalt and copper was dissolved and diluted to a volume of 100.0 mL. A solution containing ligand X was added to a 50.0 mL aliquot of the sample solution and diluted to a final volume of 100.0 mL. The measured absorbance of the unknown solution was 0.484 at 510 nm and 0.354 at 645 nm, when measured with a 1.00 cm cell. The molar absorptivities of the cobalt and copper complexes at each wavelength are shown in the table. Molar Absorptivity (e, M-¹cm-¹) Wavelength λ, nm 510 645 [Co²+] = What is the concentration of cobalt and copper in the final diluted solution? [Cu²+] = Co 36437 1241 wt% Co²+ = Cu 5526 17520 What is the weight percent of cobalt (FM = 58.933 g/mol) and copper (FM = 63.546 g/mol) in the 0.256 g sample? wt% Cu²+ == M M %
How would you calculate Ɛ from the gradient of an absorbance vs concentration plot?
3a) What is the unit of absorbance? b)When he exponential trend line of iron concentration vs time is y=4.2 exp(-0.24x) x is time in min and y is concentraion of phen iron complex solution. c)Explain the relationshipp between temperature vs decay constant and temperature vs half life. d) The concentration of iron in solution a is 5 mg/l. A total volume of solution a is 10 mL in beaker. If 20ml of phenanthroline solution is added into the solution A beaker. Wha is the final concentration of ionafter two solutions are mixed. e)Why do we need to blank or zero the specrometer??