In a zinc-copper cell, | Zn 2 (aq) || Cu·2, (aq) ), which electrode is positive? A Cu 2 C c Zn) Zn 2

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### Understanding Electrode Polarity in a Zinc-Copper Cell

In a zinc-copper cell, represented as:

\[ \text{Zn}_{(s)} | \text{Zn}^{+2}_{(aq)} || \text{Cu}^{+2}_{(aq)} | \text{Cu}_{(s)} \]

Which electrode is positive?

#### Options:

- **A.** \( \text{Cu}^{+2} \)
- **B.** \( \text{Cu}_{(s)} \)
- **C.** \( \text{Zn}_{(s)} \)
- **D.** \( \text{Zn}^{+2} \)

### Explanation:

To understand which electrode is positive in this galvanic cell, we need to examine the standard cell notation and the principles of electrochemistry:

1. **Cell Notation:** The notation \( \text{Zn}_{(s)} | \text{Zn}^{+2}_{(aq)} || \text{Cu}^{+2}_{(aq)} | \text{Cu}_{(s)} \) represents a galvanic cell where zinc metal is oxidized to zinc ions \((\text{Zn}^{+2})\), and copper ions \((\text{Cu}^{+2})\) are reduced to copper metal.
  
2. **Oxidation and Reduction:**
   - Oxidation occurs at the anode: \( \text{Zn}_{(s)} \rightarrow \text{Zn}^{+2}_{(aq)} + 2e^- \)
   - Reduction occurs at the cathode: \( \text{Cu}^{+2}_{(aq)} + 2e^- \rightarrow \text{Cu}_{(s)} \)

3. **Electrode Polarity:**
   - In a galvanic cell, the anode (where oxidation occurs) is negative.
   - The cathode (where reduction occurs) is positive.

Therefore, in the given zinc-copper cell, \( \text{Cu}_{(s)} \) (the copper solid electrode) is the positive electrode, because it is where the copper ions \((\text{Cu}^{+2})\) gain electrons (reduction) to form solid copper.

### Correct Answer:

**B.** \( \text{Cu}_{(s)} \)
Transcribed Image Text:### Understanding Electrode Polarity in a Zinc-Copper Cell In a zinc-copper cell, represented as: \[ \text{Zn}_{(s)} | \text{Zn}^{+2}_{(aq)} || \text{Cu}^{+2}_{(aq)} | \text{Cu}_{(s)} \] Which electrode is positive? #### Options: - **A.** \( \text{Cu}^{+2} \) - **B.** \( \text{Cu}_{(s)} \) - **C.** \( \text{Zn}_{(s)} \) - **D.** \( \text{Zn}^{+2} \) ### Explanation: To understand which electrode is positive in this galvanic cell, we need to examine the standard cell notation and the principles of electrochemistry: 1. **Cell Notation:** The notation \( \text{Zn}_{(s)} | \text{Zn}^{+2}_{(aq)} || \text{Cu}^{+2}_{(aq)} | \text{Cu}_{(s)} \) represents a galvanic cell where zinc metal is oxidized to zinc ions \((\text{Zn}^{+2})\), and copper ions \((\text{Cu}^{+2})\) are reduced to copper metal. 2. **Oxidation and Reduction:** - Oxidation occurs at the anode: \( \text{Zn}_{(s)} \rightarrow \text{Zn}^{+2}_{(aq)} + 2e^- \) - Reduction occurs at the cathode: \( \text{Cu}^{+2}_{(aq)} + 2e^- \rightarrow \text{Cu}_{(s)} \) 3. **Electrode Polarity:** - In a galvanic cell, the anode (where oxidation occurs) is negative. - The cathode (where reduction occurs) is positive. Therefore, in the given zinc-copper cell, \( \text{Cu}_{(s)} \) (the copper solid electrode) is the positive electrode, because it is where the copper ions \((\text{Cu}^{+2})\) gain electrons (reduction) to form solid copper. ### Correct Answer: **B.** \( \text{Cu}_{(s)} \)
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