A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e → Ag(s) + Cl(aq) Eºred = 0.2223 V And a copper electrode with 0.500 M Cu²+ as the second half cell Cu²+ (aq) + 2 e → Cu(s) Eºred= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0595 V.

Chemistry
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Chapter1: Chemical Foundations
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A student wishes to determine the
chloride ion concentration in a water
sample at 25 °C using a galvanic cell
constructed with a graphite
electrode and a half-cell of
AgCl(s) + e → Ag(s) + Cl(aq) Eºred
= 0.2223 V
And a copper electrode with 0.500 M
Cu²+ as the second half cell
Cu²+ (aq) + 2 e → Cu(s) Eºred= 0.337
V
The measured cell potential when
the water sample was placed into the
silver side of the cell was 0.0595 V.
Write the balanced equation for the
overall reaction in acidic solution.
Transcribed Image Text:A student wishes to determine the chloride ion concentration in a water sample at 25 °C using a galvanic cell constructed with a graphite electrode and a half-cell of AgCl(s) + e → Ag(s) + Cl(aq) Eºred = 0.2223 V And a copper electrode with 0.500 M Cu²+ as the second half cell Cu²+ (aq) + 2 e → Cu(s) Eºred= 0.337 V The measured cell potential when the water sample was placed into the silver side of the cell was 0.0595 V. Write the balanced equation for the overall reaction in acidic solution.
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