In a study of the decomposition of nitrosyl bromide at 10 °C NOBrNO + ½ Br2 the following data were obtained: [NOBr], M 0.249 0.125 6.25×10-2 3.13×10-2 seconds 0 6.16 18.5 43.2 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.249 M is s and when the starting concentration is 0.125 M is s. (2) The average (1/[NOBr]) / t from t = 0 s to t = 6.16 s is M-1 s-1. The average (1/[NOBr]) / t from t = 6.16 s to t = 18.5 s is M-1 s-1. (3) Based on these data, the rate constant for this     order reaction is M-1 s-1.

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In a study of the decomposition of nitrosyl bromide at 10 °C

NOBrNO + ½ Br2

the following data were obtained:

[NOBr], M 0.249 0.125 6.25×10-2 3.13×10-2
seconds 0 6.16 18.5 43.2



Hint: It is not necessary to graph these data.

(1)
The observed half life for this reaction when the starting concentration is 0.249 M is s and when the starting concentration is 0.125 M is s.

(2)
The average (1/[NOBr]) / t from t = 0 s to t = 6.16 s is M-1 s-1.
The average (1/[NOBr]) / t from t = 6.16 s to t = 18.5 s is M-1 s-1.

(3)
Based on these data, the rate constant for this 

 

 order reaction is M-1 s-1.

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