In a gaseous KCl molecule, the equilibrium internucleardistance is 2.67 × 10=10 m. Using data from Appendix Fand assuming that a Coulomb potential is a good approximation of the potential from K+ + Cl= to 2.67 3 10=10 m,estimate the dissociation energy of gaseous KCl into K andCl atoms (in kJ mo=1). (Note: Table 3.7 shows that aCoulomb potential is only a good approximation to thepotential between two charged atoms at long inter-atomicdistances; the percent ionic character of KCl at equilibrium is only 82%.)

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Chapter1: Chemical Foundations
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In a gaseous KCl molecule, the equilibrium internuclear
distance is 2.67 × 10=10 m. Using data from Appendix F
and assuming that a Coulomb potential is a good approximation of the potential from K+ + Cl= to 2.67 3 10=10 m,
estimate the dissociation energy of gaseous KCl into K and
Cl atoms (in kJ mo=1). (Note: Table 3.7 shows that a
Coulomb potential is only a good approximation to the
potential between two charged atoms at long inter-atomic
distances; the percent ionic character of KCl at equilibrium is only 82%.)

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