8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by,citationleggW, = 0.205,H +0.98º3p,cI%Dght ventricFULL PRICwhere ø is the (normalized) hydrogen 1s orbital and o,, c is the (normalized) chlorineBOG3pz orbital. Assume that the atomic overlap integral is zero, | WisH W3p.cadt = 0.%3Dall spacea) Show that the bonding molecular orbital is normalized.Shot232 PMBOOand B,b) What is the energy of the bonding orbital? Write your answer in terms of a,, ,a,,.T COSwhich are defined by:АМShbt25PMght ventric| V1s,HHw cdt = |4 1s,HRENT &||all spaceall spaceChepulmcvein| Wis.H HySHdt =a,, andcdt = d3p.1s,3 Pz,CIrightatriursen Shot2021-02 5.56 PMpulmonaryvalveall spaceall spaceWétv AAPR 429260Book ADDF11F10

Given the HCl bonding orbital as, Where 0.20 and 0.98 are individual coefficients of normalisation…

8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, W, = 0.200,H +0.989,,, C where is the (normalized) hydrogen 1s orbital and , a is the (normalized) chlorine 3pz orbital. Assume that the atomic overlap integral is zero, YW3P.cdt =0. all space a) Show that the bonding molecular orbital is normalized. b) What is the energy of the bonding orbital? Write your answer in terms of a,,a,, and B, which are defined by: S Wop,ci Hwdr = ß all space all space %3D | Vis. Hyudt = a, and ] Wap.c Hwap.cd7 = d;p. %3D | V1s,H all space all space

8) Consider the heteronuclear diatomic molecule, HCl with bonding orbital given by, W, = 0.200,H +0.989,,, C where is the (normalized) hydrogen 1s orbital and , a is the (normalized) chlorine 3pz orbital. Assume that the atomic overlap integral is zero, YW3P.cdt =0. all space a) Show that the bonding molecular orbital is normalized. b) What is the energy of the bonding orbital? Write your answer in terms of a,,a,, and B, which are defined by: S Wop,ci Hwdr = ß all space all space %3D | Vis. Hyudt = a, and ] Wap.c Hwap.cd7 = d;p. %3D | V1s,H all space all space

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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