Imagine that the staggered and eclipsed conformers of a small, saturated hydrocarbon are separated in energy by 1.5 kcal/mol. Given this information, what fraction of the molecules would be in the staggered conformation at any given instant? Assume that the sample is at thermal equilibrium at 25 °C, and enter your answer to the nearest hundredth. For example, if the fraction you determined was 1/2, you would enter 0.50 as your answer. Hint: the gas constant, R, equals 1.987 cal/K·mol and T in Kelvin equals the temperature in Celsius + 273; also, assume that all the molecules are either staggered or eclipsed. |
Imagine that the staggered and eclipsed conformers of a small, saturated hydrocarbon are separated in energy by 1.5 kcal/mol. Given this information, what fraction of the molecules would be in the staggered conformation at any given instant? Assume that the sample is at thermal equilibrium at 25 °C, and enter your answer to the nearest hundredth. For example, if the fraction you determined was 1/2, you would enter 0.50 as your answer. Hint: the gas constant, R, equals 1.987 cal/K·mol and T in Kelvin equals the temperature in Celsius + 273; also, assume that all the molecules are either staggered or eclipsed. |
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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