(iii) Write out the expression for the approximate form of the Marcus-Hush equation for a heteronuclear redox reaction and briefly define each of its terms. (iv) Utilise the Marcus-Hush equation to calculate the rate constant k12 for the cross-reaction between the above complexes: [Ru(NH3)6]2+ + [Co(NH3)6]³+ → [Ru(NH3)6]³+ + [Co(NH3)6]²+ The following data are given: K₁1 = 104 M-¹ S-¹ k22 = 106 M-¹ S-1 fiz = 1 K12 = 344.

(iii) Write out the expression for the approximate form of the Marcus-Hush equation for a heteronuclear redox reaction and briefly define each of its terms. (iv) Utilise the Marcus-Hush equation to calculate the rate constant k12 for the cross-reaction between the above complexes: [Ru(NH3)6]2+ + [Co(NH3)6]³+ → [Ru(NH3)6]³+ + [Co(NH3)6]²+ The following data are given: K₁1 = 104 M-¹ S-¹ k22 = 106 M-¹ S-1 fiz = 1 K12 = 344.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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