IIIO Chemical ReactionsSolving for a reactant in solution3/5BOne way in which the useful metal copper is produced is by dissolving the mineral azurite, which contains copper(II) carbonate, in concentrated sulfuric acid.The sulfuric acid reacts with the copper(II) carbonate to produce a blue solution of copper(II) sulfate. Scrap iron is then added to this solution, and pure coppermetal precipitates out because of the following chemical reaction:Fe(s) + CuSO4(aq) → Cu(s) + FeSO4(aq)Suppose an industrial quality-control chemist analyzes a sample from a copper processing plant in the following way. He adds powdered iron to a 200. mLcopper(II) sulfate sample from the plant until no more copper will precipitate. He then washes, dries, and weighs the precipitate, and finds that it has a mass of63. mg.Calculate the original concentration of copper(II) sulfate in the sample. Round your answer to 2 significant digits.

Answered: III O Chemical Reactions Solving for a…

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter9: Chemical Reactions

Section: Chapter Questions

Problem 139A

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According to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?
Name the reagent, if any, that you would add to a solution of iron(lll) chloride to precipitate (a) iron(lll) hydroxide. (b) iron(lll) carbonate. (c) iron(lll) phosphate.
Relative solubilities of salts in liquid ammonia can differsignificantly from those in water. Thus, silver bromide issoluble in ammonia, but barium bromide is not (thereverse of the situation in water). Write a balanced equation for the reaction of anammonia solution of barium nitrate with an ammoniasolution of silver bromide. Silver nitrate is soluble inliquid ammonia. What volume of a 0.50 M solution of silver bromidewill react completely with 0.215 L of a 0.076 M solutionof barium nitrate in ammonia? What mass of barium bromide will precipitate fromthe reaction in part (b)?
Lead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?
Describe in words how you would prepare pure crystalline AgCl and NaNO3 from solid AgNO3 and solid NaCl.
Calcium carbonate, CaCO3, can be obtained in a very pure state. Standard solutions of calcium ion are usually prepared by dissolving calcium carbonate in acid. What mass of CaCO3 should be taken to prepare 500. mL of 0.0200 M calcium ion solution?
42. a. Fill in the following table as if it is a well plate and you are mixing two aqueous compounds at a time to see if a precipitate forms. If a precipitate is expected to form, indicate that by writing the correct formula for the precipitate in the corresponding box in the table. If no precipitate is expected to form, write “NO” in the box. CaCI2 Pb(NO3)2 (NH4)3PO4 Na2CO3 AgNO3 K2SO4 b. How do you prepare 300.0 mL of a 0.250 M CaCl2 solution using an available 2(X) M solution? Support your answer with calculations, but also make sure you describe how to prepare the solution.
On the basis of the general solubility rules given in Table 7.1, predict which of the following substances are not likely to be soluble in water. Indicate which specific rule(s) led to your conclusion. :math>PbSe. BaCO3 :math>Mg(OH)2f. AlPO4 :math>Na2SO4g. PbCl2 :math>(NH4)2Sh. CaSO4
One method for determining the purity of aspirin (C9H8O4) is to hydrolyze it with NaOH solution and then to titrate the remaining NaOH. The reaction of aspirin with NaOH is as follows: A sample of aspirin with a mass of 1.427 g was boiled in 50.00 mL of 0.500 M NaOH. After the solution was cooled, it took 31.92 mL of 0.289 M HCl to titrate the excess NaOH. Calculate the purity of the aspirin. What indicator should be used for this titration? Why?
Polychlorinated biphenyls (PCBs) have been used extensively as dielectric materials in electrical transformers. Because PCBs have been shown to be potentially harmful, analysis for their presence in the environment has become very important. PCBs are manufactured according to the following generic reaction: C12H10+nCl2C12H10nCln.+nHCl This reaction results in a mixture of PCB products. The mixture is analyzed by decomposing the PCBs and then precipitating the resulting Cl asAgCl. a. Develop a general equation that relates the average value of n to the mass of a given mixture of PCBs and the mass of AgCl produced. b. A 0.1947-g sample of a commercial PCB yielded 0.4791 g of AgCl. What is the average value of n for this sample?
Separate samples of a solution of an unknown soluble ionic compound are treated with KCl, Na2SO4, and NaOH. A precipitate forms only when Na2SO4 is added. Which cations could be present in the unknown soluble ionic compound?
A 300.0-g sample of a solid is made up of a uniform mixture of NaNO3, MgCl2, and BaCl2. A 100.0-g sample of the mixture is dissolved in water and treated with an excess of KOH. The precipitate from the reaction has a mass of 13.47 g. The remaining 200.0-g sample is also dissolved in water and treated with an aqueous solution of AgNO3. The resulting precipitate has a mass of 195.8 g. What are the masses of NaNO3, MgCl2, and BaCl2 in the 300.0-g sample?

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