II. REACTION EQUILIBRIA INVOLVING PURE LIQUIDS OR PURE SOLIDS AG°r,298 values for BaSO4(s), Ba2*(aq), and SO42-(aq) are -1362.31, -560.74, and -744.63 kJ/mol, respectively. a) Find Ksp for BaSO4 in water at 25 °C. b) Calculate the solubility of BaSO4 in pure water at 25°C. c) Calculate the solubility of BaSO4 in a 0.1 mol/kg K2SO4 (aq) solution at 25°C. d) Compare the results obtained in (b) and (c). Note: Neglect ion pairing. DATA: AG° = -RTINKº (Y+)®+ (m,)"+ (m_)"- v_) log yt = - 0.51 Z4ĮZ_| - 0.30 (m/mº. то 1+m2 Im = E 2}.m; m°= 1 mol/kg

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II. REACTION EQUILIBRIA INVOLVING PURE LIQUIDS OR PURE SOLIDS
AG°;,298 values for BaSO4(s), Ba²*(aq), and SO22-(aq) are -1362.31, -560.74,
and -744.63 kJ/mol, respectively.
a) Find Ksp for BaSO4 in water at 25 °C.
b) Calculate the solubility of BaSO4 in pure water at 25°C.
c) Calculate the solubility of BaSO4 in a 0.1 mol/kg K2SO4 (aq) solution
at 25°C.
d) Compare the results obtained in (b) and (c).
Note: Neglect ion pairing.
DATA:
AG° = –RTlnKº
Ksp = (Y+)"+
+v_)
(m,)"+(m_)"-
log yt = - 0.51 z,]Z_|
0.30 ('m/mo)
[1+m2
mo)
Im = E 2}. m;
m°= 1 mol/kg
< >
Transcribed Image Text:II. REACTION EQUILIBRIA INVOLVING PURE LIQUIDS OR PURE SOLIDS AG°;,298 values for BaSO4(s), Ba²*(aq), and SO22-(aq) are -1362.31, -560.74, and -744.63 kJ/mol, respectively. a) Find Ksp for BaSO4 in water at 25 °C. b) Calculate the solubility of BaSO4 in pure water at 25°C. c) Calculate the solubility of BaSO4 in a 0.1 mol/kg K2SO4 (aq) solution at 25°C. d) Compare the results obtained in (b) and (c). Note: Neglect ion pairing. DATA: AG° = –RTlnKº Ksp = (Y+)"+ +v_) (m,)"+(m_)"- log yt = - 0.51 z,]Z_| 0.30 ('m/mo) [1+m2 mo) Im = E 2}. m; m°= 1 mol/kg < >
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