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Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 12.54PAE

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Question

Copper (II) Phosphate is extremely insoluble, but forms a complex ion with CN^- that can drive the Copper (II) solubility through Le Chatlier’s principle. Given the two reactions below, determine K_T.

Cu₃(PO₄)_{2 (s)} -->3 Cu²⁺ (aq) + 2 PO₄^3-(aq) K₁=2.05x10^-35

Cu(CN)₄^2- (aq) -->Cu²⁺ (aq) + 4 CN^- (aq) K₂=1.0x10^-25

Cu₃(PO₄)_{2 (s)} + 12 CN^- (aq) --> 3 Cu(CN)₄^2- (aq) + 2 PO₄^3- (aq) K_T=???

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