If in the following mechanism, the entering Y ligand could not follow the top path but follows the middle and bottom paths with equal probability, what percent of the product complex will consist of the trans isomer? Group of answer choices 66.67% 100% 50% 33.33%
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If in the following mechanism, the entering Y ligand could not follow the top path but follows the middle and bottom paths with equal probability, what percent of the product complex will consist of the trans isomer?
Group of answer choices 66.67% 100% 50% 33.33%
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- In the mechanism of ligand exchange in the following reaction, [Co(NH3)6]²* + co the common intermediate that could occur in this reaction is .... NH3 NH3 H3N, Co. H3N NH3 CO A H3N, NH3 Co. NH3 H3N CO B NH3 NH3 H3N, Co CO H3N NH3 C NH3Consider a kinetics study of the following ligand substitution reaction: trans-[Rh(en)2Cl2] + + 2 Y− trans-[Rh(en)2Y2] + + 2 Cl− When Y− = I−, Br−, and NO2 −, the reaction rate constants are 5.2 x 10-5 , 4.0 x 10-5 , and 4.2 x 10-5 M-1 s-1 , respectively. By which mechanism does this reaction most likely proceed? Justify your answer.Give the starting material and mechanism arrows needed to produce the given product by coordination. ÖⓇ-H H
- 5) Consider the rhodium complex below. Reaction with 1 equivalent of oxygen gas oxidizes the metal centre and gives a new complex with cis, distorted octahedral geometry. Draw the structure of the product and give the oxidation state, valence electron count, and d-electron count for both rhodium complexes. Ar 1 eq. O2 Ph3P. Rh Ph3P -"Bu ?ROTECT-A BEDO Draw the detailed mechanisms for the following transition metal complex catalyzed transformations. 550W Hg lamp Pyrex filter 1. 0 °C, 28h; 65% H. (solvent)4. Which complex will have faster kinetics for the reaction below? Justify. *-* PBU X = Pr (Bu Pr Bu cone 160° 182° angle
- Which of the following compound/s are correct in the given statements? 1.What compound/s will be able to get the change in the color of AlCl3 Crystal? If tert-butyl chloride is added in AlCl3. 2. Which compound will react in water under under light conditions with Br2? 3. Which compound will react in Kl under under dark conditions with I2?Draw the sigma complexConsider this ligand substitution mechanism where the three main paths are equally likely to occur and at every path branching point, the subsequent routes are equally likely to occur. Which of the following statements is false? -x, B (a) +Y, B trans 45 →>> XAB X AB If these 3 intermediate geometries are equally likely to occur: 13 1/3 (b) B B trans B 13 B SA 0 B ہے. B D Δ If each of these products were equally likely to form: The percent of trans product isomer that forms will be at least 50%. ○ In the bottom path, the Y ligand cannot enter on left side of the trigonal plane because an ethylenediamine ligand bridge (that connects the two -NH2 groups) blocks that side. The percent of A product isomer that forms will be less than 20%. ○ The three complexes shown at the beginning of the reactions paths - the molecules with the "1/3" numbers underneath them - are the same complex shown from different geometric perspectives. This is possible because the complex has an octahedral geometry.
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