I need help with 4 and 5? Also I need help using the 4a equation using the the generic equation the thing I circled in the second picture

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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I need help with 4 and 5? Also I need help using the 4a equation using the the generic equation the thing I circled in the second picture 

## Lab 7: Periodic Trends – Prelab and Procedure

### Figure 1: Qualitative Energy Changes in the Dissolution Process of NaCl

The diagram illustrates the energy changes in the dissolution process of sodium chloride (NaCl). It involves three steps:

1. **Lattice Energy:** 
   - Transition from solid NaCl to gaseous ions: \( \text{NaCl (s)} \rightarrow \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(g)} \)

2. **Hydration Energy of Anion:**
   - Hydration of chloride ions: \( \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(g)} \rightarrow \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(aq)} \)

3. **Hydration Energy of Cation:**
   - Hydration of sodium ions: \( \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(aq)} \rightarrow \text{Na}^+ \text{(aq)} + \text{Cl}^- \text{(aq)} \)

**Explanation of Energy Concepts:**

- **Ionic Solubility:** Solubility is influenced by the balance of lattice energy and hydration energy. A negative or slightly positive sum of these energies typically favors dissolution due to random molecular motion.
- **Charge Density:** This affects hydration energy. Higher charge density leads to greater hydration energy. The goal is to observe trends in alkaline earth cations’ precipitation with anions.

### Part B – Reactivity of Halogens (Group VIIA)

In this part, the focus is on trends in diatomic halogen reactivity (Cl\(_2\), Br\(_2\), I\(_2\)). The experiment involves halogen-halide ion reactions in a series of tests:
 
**Reaction Setup:**
- A molecular halogen \( X_2 \) may take an electron from a halide ion \( Y^- \). If successful, the following reaction occurs:
  \[
  X_2 \text{(aq)} + 2 Y^- \text{(aq)} \rightarrow Y_2 \text{(aq)} + 2 X^- \text{(aq)}
  \
Transcribed Image Text:## Lab 7: Periodic Trends – Prelab and Procedure ### Figure 1: Qualitative Energy Changes in the Dissolution Process of NaCl The diagram illustrates the energy changes in the dissolution process of sodium chloride (NaCl). It involves three steps: 1. **Lattice Energy:** - Transition from solid NaCl to gaseous ions: \( \text{NaCl (s)} \rightarrow \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(g)} \) 2. **Hydration Energy of Anion:** - Hydration of chloride ions: \( \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(g)} \rightarrow \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(aq)} \) 3. **Hydration Energy of Cation:** - Hydration of sodium ions: \( \text{Na}^+ \text{(g)} + \text{Cl}^- \text{(aq)} \rightarrow \text{Na}^+ \text{(aq)} + \text{Cl}^- \text{(aq)} \) **Explanation of Energy Concepts:** - **Ionic Solubility:** Solubility is influenced by the balance of lattice energy and hydration energy. A negative or slightly positive sum of these energies typically favors dissolution due to random molecular motion. - **Charge Density:** This affects hydration energy. Higher charge density leads to greater hydration energy. The goal is to observe trends in alkaline earth cations’ precipitation with anions. ### Part B – Reactivity of Halogens (Group VIIA) In this part, the focus is on trends in diatomic halogen reactivity (Cl\(_2\), Br\(_2\), I\(_2\)). The experiment involves halogen-halide ion reactions in a series of tests: **Reaction Setup:** - A molecular halogen \( X_2 \) may take an electron from a halide ion \( Y^- \). If successful, the following reaction occurs: \[ X_2 \text{(aq)} + 2 Y^- \text{(aq)} \rightarrow Y_2 \text{(aq)} + 2 X^- \text{(aq)} \
1) Rank the alkali metal cations (Na⁺, K⁺, Rb⁺, and Cs⁺) from smallest to largest ionic radius.

2) Consider the charges and atomic radii of each alkali metal. Then rank the alkali metal cations from lowest to highest charge density (i.e., charge per atomic volume).

3) Based on your answers to 1 and 2 above, predict which alkali metal cation exhibits the greatest hydration energy.

4)
a) Write the equation for the reaction that would occur between aqueous bromide ion (Br⁻) and aqueous chlorine (Cl₂). (Hint: See generic equation in the Introduction.)

b) If this reaction occurs, which halogen (Cl or Br) has a greater ability to attract electrons?

5)
a) Write the equation for the reaction that would occur between aqueous chloride ion (Cl⁻) and aqueous bromine (Br₂).

b) Can both of the reactions in questions 4a and 5a be favorable (as in, will they occur?) under the same conditions? Answer either YES or NO.
Transcribed Image Text:1) Rank the alkali metal cations (Na⁺, K⁺, Rb⁺, and Cs⁺) from smallest to largest ionic radius. 2) Consider the charges and atomic radii of each alkali metal. Then rank the alkali metal cations from lowest to highest charge density (i.e., charge per atomic volume). 3) Based on your answers to 1 and 2 above, predict which alkali metal cation exhibits the greatest hydration energy. 4) a) Write the equation for the reaction that would occur between aqueous bromide ion (Br⁻) and aqueous chlorine (Cl₂). (Hint: See generic equation in the Introduction.) b) If this reaction occurs, which halogen (Cl or Br) has a greater ability to attract electrons? 5) a) Write the equation for the reaction that would occur between aqueous chloride ion (Cl⁻) and aqueous bromine (Br₂). b) Can both of the reactions in questions 4a and 5a be favorable (as in, will they occur?) under the same conditions? Answer either YES or NO.
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