I) II) R3C------H-CI R3C------H-…CI Reaction Profile Diagram Reaction Profile Diagram III) IV) R3C--H-----CI R3C---H-----CI Reaction Profile Diagram Reaction Profile Diagram Energy Energy Energy Energy

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(2) In radical chlorination, the key propagation step is hydrogen abstraction. This is exothermic because chlorination forms a strong H-Cl bond (103 kcal/mol). According to the Hammond Postulate, the reaction profile and transition state would be predicted to look like

 

  1. A) I
  2. B) II
  3. C) III
  4. D) IV
The image consists of four reaction profile diagrams, each illustrating a chemical reaction involving R3C, H, and Cl. The x-axis in all diagrams is labeled "Reaction Profile Diagram," and the y-axis is labeled "Energy."

I) The first diagram shows a typical energy curve with a single peak, indicating a transition state. The notation is R3C—H––Cl, suggesting an interaction between the chemical species.

II) The second diagram also displays an energy profile with a peak. The curve rises, reaches a transition state, and then falls back, depicting the energy changes during the reaction. The interacting species are again denoted as R3C—H––Cl.

III) The third diagram has a similar shape to the first, with a peak indicating the transition state. The energy changes follow the pattern R3C—H––Cl.

IV) The fourth diagram shows an energy profile with a peak that is slightly skewed compared to the others, representing a different energy transformation. The species involved are labeled as R3C—H––Cl.

Each diagram visualizes the energy changes during the reaction process, highlighting transition states where the highest energy exists.
Transcribed Image Text:The image consists of four reaction profile diagrams, each illustrating a chemical reaction involving R3C, H, and Cl. The x-axis in all diagrams is labeled "Reaction Profile Diagram," and the y-axis is labeled "Energy." I) The first diagram shows a typical energy curve with a single peak, indicating a transition state. The notation is R3C—H––Cl, suggesting an interaction between the chemical species. II) The second diagram also displays an energy profile with a peak. The curve rises, reaches a transition state, and then falls back, depicting the energy changes during the reaction. The interacting species are again denoted as R3C—H––Cl. III) The third diagram has a similar shape to the first, with a peak indicating the transition state. The energy changes follow the pattern R3C—H––Cl. IV) The fourth diagram shows an energy profile with a peak that is slightly skewed compared to the others, representing a different energy transformation. The species involved are labeled as R3C—H––Cl. Each diagram visualizes the energy changes during the reaction process, highlighting transition states where the highest energy exists.
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