I am interested in calculating the carbon system. I know that two of the four CO2 properties (ΣCO2, PCO2, pH, and carbonate alkalinity) can be used to determine the entire CO2 system, but I dont know the equations that can be used to relate a set of properties to the whole system. How can I use pH and ΣCO2 to calculate PCO2 and carbonate alkalinity? Or ΣCO2 and carbonate alkalinity to calculate the speciation of each carbon species?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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I am interested in calculating the carbon system. I know that two of the four CO2 properties (ΣCO2, PCO2, pH,
and carbonate alkalinity) can be used to determine the entire CO2 system, but I dont know the equations that can be used to relate a set of properties to the whole system. How can I use pH and ΣCO2 to calculate PCO2 and carbonate alkalinity? Or ΣCO2 and carbonate alkalinity to calculate the speciation of each carbon species?

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