Hydrofluoric acid, HF(aq), cannot be stored in glass bottles because compounds called silicates in the glass are attacked by the HF(aq). For example, sodium silicate, Na2SiO3, reacts in the following way

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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(1) Hydrofluoric acid, HF(aq), cannot be stored in glass bottles because compounds called silicates in the glass are attacked by the HF(aq). For example, sodium silicate, Na2SiO3, reacts in the following way

Na2SiO3(s)  +  8   HF(aq)   →     H2SiF6 (aq) +   2  NaF(aq) + 3   H2O(l)

     Atomic weights (g/mol): Na=23, Si=28, O=16, H=1, F=19

(c) How much each (in grams) of NaF(aq) and water will be produced from 9.0 moles of hydrofluoric acid?

(d) If 200 grams of HF(aq) attacked 1.5 moles sodium silicate , identify the limiting and excess reagents

(e) How much of the excess reagent remains unreacted?

(f)   If the reaction in (d) produces 40.0 grams of NaF, calculate the percent yield.

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