How to find the order of the reaction

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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How to find the order of the reaction
Рензоснз
(mm Hg)
Time (s)
312
0
426
278
390
717
points (an graphis).
251
777
2
227
1195
0.903
157
3155
0 103 )
Transcribed Image Text:Рензоснз (mm Hg) Time (s) 312 0 426 278 390 717 points (an graphis). 251 777 2 227 1195 0.903 157 3155 0 103 )
Expert Solution
Step 1: Introduction of Order of reaction

If the reaction is zero order, a plot of pressure vs. time will be linear. The formula for a zero-order reaction is: 

box enclose P equals P subscript o plus space k t end enclose

If the reaction is first order, a plot of the natural logarithm of pressure vs. time will be linear. The formula for a first-order reaction is:

box enclose ln space P equals ln space P subscript o plus space k t end enclose

If the reaction is second order, a plot of the reciprocal of pressure vs. time will be linear. The formula for a second-order reaction is:

box enclose 1 over P equals 1 over P subscript o plus space k t end enclose

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