Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![**Title: Chemistry Problem - Molarity and Stoichiometry**
**Problem Statement:**
How many milliliters (mL) of 0.776 M HCl are needed to dissolve 6.95 grams of CaCO₃?
**Chemical Reaction:**
\[ 2\text{HCl}(aq) + \text{CaCO}_3(s) \rightarrow \text{CaCl}_2(aq) + \text{H}_2\text{O}(l) + \text{CO}_2(g) \]
\[ \fbox{ } \text{ mL} \]
---
**Explanation:**
This problem involves using the principles of molarity and stoichiometry to determine the volume of hydrochloric acid (HCl) needed to fully react with a given amount of calcium carbonate (CaCO₃).
1. **Identify the Chemical Equation:** The balanced chemical equation is provided, illustrating that 2 moles of hydrochloric acid react with 1 mole of calcium carbonate to produce calcium chloride, water, and carbon dioxide.
2. **Calculate Moles of CaCO₃:**
- First, determine the molar mass of CaCO₃:
- Calcium (Ca): 40.08 g/mol
- Carbon (C): 12.01 g/mol
- Oxygen (O): 16.00 g/mol × 3 = 48.00 g/mol
- Total molar mass of CaCO₃ = 40.08 + 12.01 + 48.00 = 100.09 g/mol
- Calculate moles of CaCO₃:
\[ \text{Moles of CaCO₃} = \frac{\text{mass}}{\text{molar mass}} = \frac{6.95 \text{ g}}{100.09 \text{ g/mol}} \approx 0.0694 \text{ mol} \]
3. **Use Stoichiometry to Find Moles of HCl Needed:**
- According to the balanced equation, 2 moles of HCl are required for every 1 mole of CaCO₃.
- Moles of HCl needed = 0.0694 mol CaCO₃ × 2 mol HCl / 1 mol CaCO₃ = 0.1388 mol HCl
4. **Calculate Volume](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F84435934-315d-4f3f-bf89-3ba66c6d068b%2Fb8d56db5-12be-4433-89c5-4a5f536a7798%2Fw394rav_processed.png&w=3840&q=75)
Transcribed Image Text:**Title: Chemistry Problem - Molarity and Stoichiometry**
**Problem Statement:**
How many milliliters (mL) of 0.776 M HCl are needed to dissolve 6.95 grams of CaCO₃?
**Chemical Reaction:**
\[ 2\text{HCl}(aq) + \text{CaCO}_3(s) \rightarrow \text{CaCl}_2(aq) + \text{H}_2\text{O}(l) + \text{CO}_2(g) \]
\[ \fbox{ } \text{ mL} \]
---
**Explanation:**
This problem involves using the principles of molarity and stoichiometry to determine the volume of hydrochloric acid (HCl) needed to fully react with a given amount of calcium carbonate (CaCO₃).
1. **Identify the Chemical Equation:** The balanced chemical equation is provided, illustrating that 2 moles of hydrochloric acid react with 1 mole of calcium carbonate to produce calcium chloride, water, and carbon dioxide.
2. **Calculate Moles of CaCO₃:**
- First, determine the molar mass of CaCO₃:
- Calcium (Ca): 40.08 g/mol
- Carbon (C): 12.01 g/mol
- Oxygen (O): 16.00 g/mol × 3 = 48.00 g/mol
- Total molar mass of CaCO₃ = 40.08 + 12.01 + 48.00 = 100.09 g/mol
- Calculate moles of CaCO₃:
\[ \text{Moles of CaCO₃} = \frac{\text{mass}}{\text{molar mass}} = \frac{6.95 \text{ g}}{100.09 \text{ g/mol}} \approx 0.0694 \text{ mol} \]
3. **Use Stoichiometry to Find Moles of HCl Needed:**
- According to the balanced equation, 2 moles of HCl are required for every 1 mole of CaCO₃.
- Moles of HCl needed = 0.0694 mol CaCO₃ × 2 mol HCl / 1 mol CaCO₃ = 0.1388 mol HCl
4. **Calculate Volume
![**Reaction Stoichiometry Calculation**
In this exercise, we aim to calculate the number of milliliters of a 0.689 M NaOH solution required to precipitate all of the Al³⁺ ions present in 163 mL of a 0.784 M Al₂(SO₄)₃ solution.
**Chemical Reaction:**
The balanced chemical equation for the reaction is:
\[ \text{Al}_2(\text{SO}_4)_3 (\text{aq}) + 6\text{NaOH} (\text{aq}) \rightarrow 2\text{Al}(\text{OH})_3 (\text{s}) + 3\text{Na}_2\text{SO}_4 (\text{aq}) \]
**Calculation Steps:**
1. **Determine Moles of Al₂(SO₄)₃:**
- Molarity (M) of Al₂(SO₄)₃ = 0.784 M
- Volume (V) of Al₂(SO₄)₃ = 163 mL = 0.163 L
- Moles of Al₂(SO₄)₃ = Molarity × Volume = 0.784 M × 0.163 L
2. **Relate Moles of Al₂(SO₄)₃ to Moles of NaOH:**
- From the balanced equation, 1 mole of Al₂(SO₄)₃ reacts with 6 moles of NaOH.
3. **Calculate Volume of NaOH Solution Required:**
- Molarity (M) of NaOH = 0.689 M
- Moles of NaOH = (Moles of Al₂(SO₄)₃) × 6
- Volume of NaOH = Moles of NaOH / Molarity of NaOH
By following these steps, we can find out the volume in milliliters of the NaOH solution needed.
**Volume Calculation:**
\[ \text{Volume} = \boxed{\text{ }} \text{mL} \]
This computational step is crucial in helping students understand reaction stoichiometry, as well as the practical application of balancing chemical equations in real-world laboratory settings.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F84435934-315d-4f3f-bf89-3ba66c6d068b%2Fb8d56db5-12be-4433-89c5-4a5f536a7798%2Fzxqjyia_processed.png&w=3840&q=75)
Transcribed Image Text:**Reaction Stoichiometry Calculation**
In this exercise, we aim to calculate the number of milliliters of a 0.689 M NaOH solution required to precipitate all of the Al³⁺ ions present in 163 mL of a 0.784 M Al₂(SO₄)₃ solution.
**Chemical Reaction:**
The balanced chemical equation for the reaction is:
\[ \text{Al}_2(\text{SO}_4)_3 (\text{aq}) + 6\text{NaOH} (\text{aq}) \rightarrow 2\text{Al}(\text{OH})_3 (\text{s}) + 3\text{Na}_2\text{SO}_4 (\text{aq}) \]
**Calculation Steps:**
1. **Determine Moles of Al₂(SO₄)₃:**
- Molarity (M) of Al₂(SO₄)₃ = 0.784 M
- Volume (V) of Al₂(SO₄)₃ = 163 mL = 0.163 L
- Moles of Al₂(SO₄)₃ = Molarity × Volume = 0.784 M × 0.163 L
2. **Relate Moles of Al₂(SO₄)₃ to Moles of NaOH:**
- From the balanced equation, 1 mole of Al₂(SO₄)₃ reacts with 6 moles of NaOH.
3. **Calculate Volume of NaOH Solution Required:**
- Molarity (M) of NaOH = 0.689 M
- Moles of NaOH = (Moles of Al₂(SO₄)₃) × 6
- Volume of NaOH = Moles of NaOH / Molarity of NaOH
By following these steps, we can find out the volume in milliliters of the NaOH solution needed.
**Volume Calculation:**
\[ \text{Volume} = \boxed{\text{ }} \text{mL} \]
This computational step is crucial in helping students understand reaction stoichiometry, as well as the practical application of balancing chemical equations in real-world laboratory settings.
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