he rigid rotor approximation
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Please do not rely too much on chatgpt, because its answer may be wrong. Please consider it carefully and give your own answer. You can borrow ideas from gpt, but please do not believe its answer.Very very grateful!Please do not rely too much on chatgpt, because its answer may be wrong. Please consider it carefully and give your own answer. You can borrow ideas from gpt, but please do not believe its answer.
and and Very very grateful!
Transcribed Image Text:3 Rotational Spectroscopy
(A)
The spacing between the lines in the microwave spectrum of H35 Cl is 6.350 x 1011
Hz. Calculate the bond length of H35 Cl.
(B)
When we discussed the selection rules for the harmonic oscillator, we computed
the magnitude of a transition between states n and n' via the expression < n|fz|n' >. Using
z = cos(0), show that the rotational transition from J=0 → J = 1 is allowed, but J = 0→J=2
is forbidden within the rigid rotor approximation approximation for any value of m. Hint: Integrate
> first; you may discover that you don't actually have to solve every integral.
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