H₂C- -CH₂ Gently warmed R H₂CH 65 H₂C- CH₂ -CH₂ H₂C CH₂ 1a) is the diene in the correct s-cis orientation to react? 1b) Would you describe the dienophile as having the ketone groups cis or trans? 1c) When you start with this cis-dienophile, what orientation must the ketone branches have to one another in the product?
H₂C- -CH₂ Gently warmed R H₂CH 65 H₂C- CH₂ -CH₂ H₂C CH₂ 1a) is the diene in the correct s-cis orientation to react? 1b) Would you describe the dienophile as having the ketone groups cis or trans? 1c) When you start with this cis-dienophile, what orientation must the ketone branches have to one another in the product?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![H₂C-
6
-CH₂
Gently warmed
H₂Cl H
H₂C-
65
CH₂
-CH₂
5
H₂C
CH₂
1a) Is the diene in the correct s-cis orientation to react?
1b) Would you describe the dienophile as having the ketone groups cis or trans?
1c) When you start with this cis-dienophile, what orientation must the ketone branches have to one another in the product?
1d) In this product, the dienophile approached from below pushing the 1 C bridge upwards. Which carbon of the product has an error as a result of the
reaction's stereospecificity?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd699f1eb-e5fa-4de3-9b57-bfcf3e532a4b%2F4949ec42-678c-4a55-94d4-759c43dc92bd%2Fhb15eo_processed.jpeg&w=3840&q=75)
Transcribed Image Text:H₂C-
6
-CH₂
Gently warmed
H₂Cl H
H₂C-
65
CH₂
-CH₂
5
H₂C
CH₂
1a) Is the diene in the correct s-cis orientation to react?
1b) Would you describe the dienophile as having the ketone groups cis or trans?
1c) When you start with this cis-dienophile, what orientation must the ketone branches have to one another in the product?
1d) In this product, the dienophile approached from below pushing the 1 C bridge upwards. Which carbon of the product has an error as a result of the
reaction's stereospecificity?
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