Hardness in groundwater is due to the presence of metal ions, primarily Mg²+ and Ca²+. Hardness is generally reported as ppm CaCO,. To measure water hardness, a sample of groundwater is titrated with EDTA, a chelating agent, in the presence of the indicator Eriochrome Black T, symbolized as In. Eriochrome Black T, a weaker chelating agent than EDTA, is red in the presence of Ca2+ and turns blue when Ca²+ is removed. red blue Ca(In)2+ +EDTA→ Ca(EDTA)²+ + In A 50.00 mL sample of groundwater is titrated with 0.0100 M EDTA. If 10.20 mL of EDTA is required to titrate the 50.00 mL sample, what is the hardness of the groundwater in molarity and in parts per million of CaCO, by mass? Assume that Ca2+ accounts for all of the hardness in the groundwater. hardness in molarity: M CACO3 hardness in parts per million: ppm CaCO3

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Hardness in groundwater is due to the presence of metal ions, primarily Mg2+ and Ca²+. Hardness is generally reported as
ppm CaCO,. To measure water hardness, a sample of groundwater is titrated with EDTA, a chelating agent, in the presence of
the indicator Eriochrome Black T, symbolized as In. Eriochrome Black T, a weaker chelating agent than EDTA, is red in the
presence of Ca²+ and turns blue when Ca2+ is removed.
red
blue
Ca(In)2+ + EDTA → Ca(EDTA)²+ + In
A 50.00 mL sample of groundwater is titrated with 0.0100 M EDTA. If 10.20 mL of EDTA is required to titrate the 50.00 mL
sample, what is the hardness of the groundwater in molarity and in parts per million of CaCO, by mass? Assume that Ca2+
accounts for all of the hardness in the groundwater.
hardness in molarity:
M CACO3
hardness in parts per million:
ppm CaCO3
Transcribed Image Text:Hardness in groundwater is due to the presence of metal ions, primarily Mg2+ and Ca²+. Hardness is generally reported as ppm CaCO,. To measure water hardness, a sample of groundwater is titrated with EDTA, a chelating agent, in the presence of the indicator Eriochrome Black T, symbolized as In. Eriochrome Black T, a weaker chelating agent than EDTA, is red in the presence of Ca²+ and turns blue when Ca2+ is removed. red blue Ca(In)2+ + EDTA → Ca(EDTA)²+ + In A 50.00 mL sample of groundwater is titrated with 0.0100 M EDTA. If 10.20 mL of EDTA is required to titrate the 50.00 mL sample, what is the hardness of the groundwater in molarity and in parts per million of CaCO, by mass? Assume that Ca2+ accounts for all of the hardness in the groundwater. hardness in molarity: M CACO3 hardness in parts per million: ppm CaCO3
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