A base is added to a 0.050 M solution of MnClz, raising the pH gradually. Calculate the pH of the solution when 88 of the manganese has precipitated?

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% of Manganese is precipitated

A base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 88 of the manganese has precipitated?
Table 5-7
Solubility-Product Constants, K, at 25°C
Fluorides
Chromates (cont.)
Ag, Cro,
PbCro,
Hydroxides (cont)
Ni(OH),
Zn(OH),
Cu(OH),
Hg(OH),
Sn(OH),
Cr(OH),
A(OH),
BaF,
MgF,
PbF,
SrF,
CaF,
2.4 x 10-5
X 10-8
x 10-8
1.9 x 10-12
1.6 x 10-16
4.5 X 10-17
1.6 x 10-19
3
2 x 10-16
4
Carbonates
7.9 x 10-10
3.9 x 10-11
X 10-26
NiCO,
CaCO,
BaCo,
SrCO,
CuCO,
ZnCO,
MnCO,
1.4 x 10-7
3
10-27
4.7 x 10-
6.7 x
5 x
6 x 10-38
2.5 x 10-43
Chlorides
10-31
1.6 x 10-
1.7 x 10-10
1.1 x 10-18
1.6 x 10-9
7 x 10-10
2.5 x 10-10
10-33
PBCI,
AgCi
Hg,Cl,
Fe(OH),
Co(OH),
Sulfides
2 x 10-10
8.8 x 10-11
2.1 x 10-11
Bromides
X 10-16
X 10-19
3 x 10-21
X 10-22
2.5 x 10-22
X 10-26
1.0 x 10-28
MnS
7.
PbBr,
AgBr
Hg, Br,
4.6 x 10-6
5.0 x 10-13
Feco
Ag,CO,
CdCo,
PBCO,
MgCO,
Hg,CO,
Fes
4
8.2 x 10-12
5.2 x 10-12
1.5 x 10-15
1 x 10-15
NiS
1.3 x 10-22
Cos
ZnS
lodides
Pbl,
Agl
Hg,1,
8.3 x 10-9
SnS
8.5 x 10-17
4.5 x 10-29
9.0 x 10-15
Cds
X 10-29
X 10-37
5.5 x 10-51
1.6 x 10-54
1.6 x 10-12
Hydroxides
Ba(OH),
Sr(OH),
Ca(OH),
AGOH
Mg(OH)2
Mn(OH),
Cd(OH)2
Pb(OH)2
Fe(OH)2
Co(OH),
PbS
7.
Sulfates
5.0 x 10-3
3.2 x 10-4
Cus
8
Caso,
Ag,so,
SrSO,
PbSo,
Baso,
2.4 x 10-5
1.2 x 10-5
1.3 x 10-8
HgS
Bi,S,
Phosphates
Ag, PO,
Sr, (PO,)2
Ca, (PO)2
Ba, (PO)2
Pb, (PO),
7.6 x 10-7
2.0 x 10-8
1.3 x 10-6
1.5 x 10-9
8.9 x 10-12
2 x 10-13
1.8 x 10-18
X 10-31
1.3 x 10-32
6 x 10-39
X 10-54
2.0 x 10-14
4.2 x 10-15
Chromates
1
SrCro,
Hg, Cro,
BaCro,
3.6 x 10-6
2 x 10-9
1.8 x 10-15
2.5 x 10-16
8.5 x 10-11
1
*As Hg+ ion. K = [Hg3 +][X-]?
from https://courses.lumenlearning.com/introchem/chapter/solubility-product/
Transcribed Image Text:A base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 88 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont) Ni(OH), Zn(OH), Cu(OH), Hg(OH), Sn(OH), Cr(OH), A(OH), BaF, MgF, PbF, SrF, CaF, 2.4 x 10-5 X 10-8 x 10-8 1.9 x 10-12 1.6 x 10-16 4.5 X 10-17 1.6 x 10-19 3 2 x 10-16 4 Carbonates 7.9 x 10-10 3.9 x 10-11 X 10-26 NiCO, CaCO, BaCo, SrCO, CuCO, ZnCO, MnCO, 1.4 x 10-7 3 10-27 4.7 x 10- 6.7 x 5 x 6 x 10-38 2.5 x 10-43 Chlorides 10-31 1.6 x 10- 1.7 x 10-10 1.1 x 10-18 1.6 x 10-9 7 x 10-10 2.5 x 10-10 10-33 PBCI, AgCi Hg,Cl, Fe(OH), Co(OH), Sulfides 2 x 10-10 8.8 x 10-11 2.1 x 10-11 Bromides X 10-16 X 10-19 3 x 10-21 X 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 7. PbBr, AgBr Hg, Br, 4.6 x 10-6 5.0 x 10-13 Feco Ag,CO, CdCo, PBCO, MgCO, Hg,CO, Fes 4 8.2 x 10-12 5.2 x 10-12 1.5 x 10-15 1 x 10-15 NiS 1.3 x 10-22 Cos ZnS lodides Pbl, Agl Hg,1, 8.3 x 10-9 SnS 8.5 x 10-17 4.5 x 10-29 9.0 x 10-15 Cds X 10-29 X 10-37 5.5 x 10-51 1.6 x 10-54 1.6 x 10-12 Hydroxides Ba(OH), Sr(OH), Ca(OH), AGOH Mg(OH)2 Mn(OH), Cd(OH)2 Pb(OH)2 Fe(OH)2 Co(OH), PbS 7. Sulfates 5.0 x 10-3 3.2 x 10-4 Cus 8 Caso, Ag,so, SrSO, PbSo, Baso, 2.4 x 10-5 1.2 x 10-5 1.3 x 10-8 HgS Bi,S, Phosphates Ag, PO, Sr, (PO,)2 Ca, (PO)2 Ba, (PO)2 Pb, (PO), 7.6 x 10-7 2.0 x 10-8 1.3 x 10-6 1.5 x 10-9 8.9 x 10-12 2 x 10-13 1.8 x 10-18 X 10-31 1.3 x 10-32 6 x 10-39 X 10-54 2.0 x 10-14 4.2 x 10-15 Chromates 1 SrCro, Hg, Cro, BaCro, 3.6 x 10-6 2 x 10-9 1.8 x 10-15 2.5 x 10-16 8.5 x 10-11 1 *As Hg+ ion. K = [Hg3 +][X-]? from https://courses.lumenlearning.com/introchem/chapter/solubility-product/
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