This EDTA solution is used to analyze a piece of 0.0630 g of metal alloy containing Sn and Cu that is dissolved in HNO3 to make a 250-mL working solution. An aliquot of 25.0 mL of the working solution requires 15.66 mL to titrate only the Sn when sodium thiosulfate is used to block the Cu. A fresh aliquot of 25.0 mL of this working solution requires 24.60 mL of EDTA to titrate both metal ions. Determine the initial mass percent (m%) of the metal alloy. (Atomic mass for Cu = 63.5 g/mol; Sn = 118.7 g/mol) {

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The concentration of EDTA is 2.497mM

This EDTA solution is used to analyze a piece of 0.0630 g of metal alloy containing Sn and Cu
that is dissolved in HNO3 to make a 250-mL working solution. An aliquot of 25.0 mL of the
working solution requires 15.66 mL to titrate only the Sn when sodium thiosulfate is used to
block the Cu. A fresh aliquot of 25.0 mL of this working solution requires 24.60 mL of EDTA to
titrate both metal ions. Determine the initial mass percent (m%) of the metal alloy. (Atomic mass
for Cu = 63.5 g/mol; Sn = 118.7 g/mol)
Transcribed Image Text:This EDTA solution is used to analyze a piece of 0.0630 g of metal alloy containing Sn and Cu that is dissolved in HNO3 to make a 250-mL working solution. An aliquot of 25.0 mL of the working solution requires 15.66 mL to titrate only the Sn when sodium thiosulfate is used to block the Cu. A fresh aliquot of 25.0 mL of this working solution requires 24.60 mL of EDTA to titrate both metal ions. Determine the initial mass percent (m%) of the metal alloy. (Atomic mass for Cu = 63.5 g/mol; Sn = 118.7 g/mol)
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