H3C- OH ACO H -H CH3 H H Aco Ac H3C - OAC Dess-Martin periodinane provides a means to oxidize a primary alcohol to aldehyde, while avoiding the use of toxic Cr(VI) compounds. The mechanism involves a reaction similar to the E2 elimination, whereby a C=O double bond is formed with a reduced iodine compound as the leaving group. The reaction occurs in a nonaqueous solvent, CH₂Cl₂, so that the aldehyde product can be recovered. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions 000 XT H3C 'Н AAQ H H3C OH H3C OAc чь

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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OH
oth
-H
H
H3C-
NX
XT
OAc
ACO
-OAc
&
O
Dess-Martin periodinane provides a means to oxidize a primary alcohol to an aldehyde, while avoiding the use of toxic Cr(VI) compounds. The mechanism involves a reaction similar to the E2
elimination, whereby a C=O double bond is formed with a reduced iodine compound as the leaving group. The reaction occurs in a nonaqueous solvent, CH₂Cl₂, so that the aldehyde product can be
recovered.
Draw curved arrows to show the movement of electrons in this step of the mechanism.
Arrow-pushing Instructions
H3C
CH3
H
ACO
$$
H
H3C
H3C
H
:0:
H H3C
OH
OAC
чь
Transcribed Image Text:OH oth -H H H3C- NX XT OAc ACO -OAc & O Dess-Martin periodinane provides a means to oxidize a primary alcohol to an aldehyde, while avoiding the use of toxic Cr(VI) compounds. The mechanism involves a reaction similar to the E2 elimination, whereby a C=O double bond is formed with a reduced iodine compound as the leaving group. The reaction occurs in a nonaqueous solvent, CH₂Cl₂, so that the aldehyde product can be recovered. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions H3C CH3 H ACO $$ H H3C H3C H :0: H H3C OH OAC чь
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