H, ннннн H3C CH3 H' H H H Acetone 1-hexene TABLE P12-22 Vapor-liquid equilib- rium of acetone(1) + 1-hexene (2) at 101.33 kPa. T[K] X, y, 336.75 331.05 0.060 0.184 327.85 0.116 0.299 326.35 0.184 0.365 324.65 0.287 0.441 323.85 0.387 0.500 323.35 0.497 0.555 323.25 0.593 0.605 323.25 0.605 0.605 323.45 0.698 0.658 324.15 0.805 0.730 325.95 0.908 0.838 329.55 1 1 Based on data fom S. K. Ogorodnkov, V. B. Kogan and M. S.Nermtsov, J. Appl.Chem. USSR 34,313 (1961).
H, ннннн H3C CH3 H' H H H Acetone 1-hexene TABLE P12-22 Vapor-liquid equilib- rium of acetone(1) + 1-hexene (2) at 101.33 kPa. T[K] X, y, 336.75 331.05 0.060 0.184 327.85 0.116 0.299 326.35 0.184 0.365 324.65 0.287 0.441 323.85 0.387 0.500 323.35 0.497 0.555 323.25 0.593 0.605 323.25 0.605 0.605 323.45 0.698 0.658 324.15 0.805 0.730 325.95 0.908 0.838 329.55 1 1 Based on data fom S. K. Ogorodnkov, V. B. Kogan and M. S.Nermtsov, J. Appl.Chem. USSR 34,313 (1961).
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Predict the Txy behavior for a mixture of acetone (1) + 1-hexene (2) at 101.33 kPa using the Peng-Robinson equation of state. Compare the predictions to the experimental data given in Table P12-22. Determine an optimal binary interaction value by defining an objective function in terms of the temperature (it can be called OBJ_T). Is the Peng-Robinson equation of state a reasonable model for this system at this state? Please explain. |
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