Given the following reactions: P.(s) + 50,(9) – P,O10(s) 2H2 (9) + Oz(g) –→ 2H;O(g) 6H;O(g) + P,O10(8) 4H,PO,(1) - 2697.0 kJ/mol – 457.18 kJ/mol AG = -428.66 kJ/mol AG AG (a) Determine the standard free energy of formation, AG°f, for phosphoric acid. (b) How does your calculated result compare to the constant thermodynamic valu from the table? Explain.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Given the following reactions:
→ P,O10(8)
→ 2H;O(g)
AG"
P,(s) + 50,(9)
2H2(9) + Oz(9)
6H;O(g) + P,O10(8) → 4H,PO,(1)
- 2697.0 kJ/mol
- 457.18 kJ/mol
AG' - -428.66 kJ/mol
AG
(a) Determine the standard free energy of formation, AG°T, for phosphoric acid.
(b) How does your calculated result compare to the constant thermodynamic value
from the table? Explain.
Transcribed Image Text:Given the following reactions: → P,O10(8) → 2H;O(g) AG" P,(s) + 50,(9) 2H2(9) + Oz(9) 6H;O(g) + P,O10(8) → 4H,PO,(1) - 2697.0 kJ/mol - 457.18 kJ/mol AG' - -428.66 kJ/mol AG (a) Determine the standard free energy of formation, AG°T, for phosphoric acid. (b) How does your calculated result compare to the constant thermodynamic value from the table? Explain.
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